2024/05/14 更新

写真a

ウエマツ ユウキ
植松 祐輝
UEMATSU Yuki
Scopus 論文情報  
総論文数: 0  総Citation: 0  h-index: 12

Citation Countは当該年に発表した論文の被引用数

メールアドレス
メールアドレス
研究室住所
福岡県飯塚市川津680-4
外部リンク

取得学位

  • 京都大学  -  博士(理学)   2016年03月

学外略歴

  • 2021年10月 - 現在   国立研究開発法人 科学技術振興機構   研究員

  • 2019年10月 - 2022年03月   九州大学   理学研究院   助教

  • 2019年02月 - 2019年12月   フランス・パリ高等師範学校   日本学術振興会海外特別研究員   フランス共和国

  • 2016年05月 - 2017年10月   ドイツ・ベルリン自由大学   訪問研究員   ドイツ連邦共和国

  • 2016年04月 - 2019年01月   九州大学   理学研究院化学部門   日本学術振興会特別研究員

論文

  • Ostwald ripening of aqueous microbubble solutions 査読有り

    Inoue S., Kimura Y., Uematsu Y.

    Journal of Chemical Physics   157 ( 24 )   2022年12月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    Bubble solutions are of growing interest because of their various technological applications in surface cleaning, water treatment, and agriculture. However, their physicochemical properties, such as the stability and interfacial charge of bubbles, are not fully understood yet. In this study, the kinetics of radii in aqueous microbubble solutions are experimentally investigated, and the results are discussed in the context of Ostwald ripening. The obtained distributions of bubble radii scaled by mean radius and total number were found to be time-independent during the observation period. Image analysis of radii kinetics revealed that the average growth and shrinkage speed of each bubble is governed by diffusion-limited Ostwald ripening, and the kinetic coefficient calculated using the available physicochemical constants in the literature quantitatively agrees with the experimental data. Furthermore, the cube of mean radius and mean volume exhibit a linear time evolution in agreement with the Lifshitz-Slezov-Wagner (LSW) theory. The coefficients are slightly larger than those predicted using the LSW theory, which can be qualitatively explained by the effect of finite volume fraction. Finally, the slowdown and pinning of radius in the shrinkage dynamics of small microbubbles are discussed in detail.

    DOI: 10.1063/5.0128696

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85145425359&origin=inward

  • Analytic theory of nonlinearly coupled electrokinetics in nanochannels 査読有り

    Uematsu Y.

    Physics of Fluids   34 ( 12 )   2022年12月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    The nonlinear electrokinetic response of ionic solutions is important in nanofluidics. However, quantitatively understanding the mechanisms is still a challenging problem because of a lack of analytic approaches. Here, a general framework for calculating the nonlinear electrokinetic coefficients of strongly confined electrolytes is constructed using a perturbation scheme of the pressure and voltage differences across a nanochannel. The theory is applied to an electrically neutral nanochannel filled with electrolytes, and analytic expressions for the first- and third-order electrokinetic coefficients are obtained. We demonstrate that the combination of high hydrodynamic permeability and ion-wall friction plays an essential role in nonlinear electrokinetics. Furthermore, we analytically demonstrate that the external flow induces uniform excess charge inside the nanochannel.

    DOI: 10.1063/5.0131481

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85144605805&origin=inward

  • Electrophoretic Mobility of a Water-in-Oil Droplet Separately Affected by the Net Charge and Surface Charge Density 査読有り

    Uematsu Y., Ohshima H.

    Langmuir   38 ( 14 )   4213 - 4221   2022年03月

     詳細を見る

    担当区分:筆頭著者, 責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    Water-in-oil emulsions and droplets exhibit physicochemical properties completely different from those of oil-in-water emulsions and droplets. Thus, directly applying a standard theoretical model to water-in-oil systems cannot describe these anomalous properties. Here, the electrophoretic mobility of a water-in-oil droplet is analytically investigated using Debye-Hückel linearization and neglecting the Marangoni effect. The resulting electrophoretic mobility is shown to be separately dependent on the net charge of the droplet and the surface charge density at the droplet interface. Furthermore, when the net charge is negligible, the electrophoretic mobility is proportional to the surface charge density with a negative coefficient. This indicates that the internal electric double layer inversely contributes to the electrophoresis. This theory is applied to experimental data of water-in-oil emulsions and droplets in the literature, and qualitative and quantitative verification of the theory is discussed.

    DOI: 10.1021/acs.langmuir.1c03145

    Scopus

    CiNii Research

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85127832685&origin=inward

  • Electrification of water interface 査読有り

    Uematsu Y.

    Journal of Physics Condensed Matter   33 ( 42 )   2021年10月

     詳細を見る

    担当区分:筆頭著者, 最終著者, 責任著者   記述言語:英語   掲載種別:記事・総説・解説・論説等(学術雑誌)

    The surface charge of a water interface determines many fundamental processes in physical chemistry and interface science, and it has been intensively studied for over a hundred years. We summarize experimental methods to characterize the surface charge densities developed so far: electrokinetics, double-layer force measurements, potentiometric titration, surface-sensitive nonlinear spectroscopy, and surface-sensitive mass spectrometry. Then, we elucidate physical ion adsorption and chemical electrification as examples of electrification mechanisms. In the end, novel effects on surface electrification are discussed in detail. We believe that this clear overview of state of the art in a charged water interface will surely help the fundamental progress of physics and chemistry at interfaces in the future 2021 IOP Publishing Ltd.

    DOI: 10.1088/1361-648X/ac15d5

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85112083877&origin=inward

  • Interfacial, Electroviscous, and Nonlinear Dielectric Effects on Electrokinetics at Highly Charged Surfaces 査読有り

    Rezaei M., Mitterwallner B.G., Loche P., Uematsu Y., Netz R.R., Bonthuis D.J.

    Journal of Physical Chemistry B   125 ( 18 )   4767 - 4778   2021年05月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    The dielectric constant and the viscosity of water at the interface of hydrophilic surfaces differ from their bulk values, and it has been proposed that the deviation is caused by the strong electric field and the high ion concentration in the interfacial layer. We calculate the dependence of the dielectric constant and the viscosity of bulk electrolytes on the electric field and the salt concentration. Incorporating the concentration and field-dependent dielectric constant and viscosity in the extended Poisson-Boltzmann and Stokes equations, we calculate the electro-osmotic mobility. We compare the results to literature experimental data and explicit molecular dynamics simulations of OH-terminated surfaces and show that it is necessary to additionally include the presence of a subnanometer wide interfacial water layer, the properties of which are drastically transformed by the sheer presence of the interface. We conclude that the origin of the anomalous behavior of aqueous interfacial layers cannot be found in electrostriction or electroviscous effects caused by the interfacial electric field and ion concentration. Instead, it is primarily caused by the intrinsic ordering and orientation of the interfacial water layer.

    DOI: 10.1021/acs.jpcb.0c11280

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85106495696&origin=inward

  • Consistent description of ion-specificity in bulk and at interfaces by solvent implicit simulations and mean-field theory 査読有り

    Dos Santos A.P., Uematsu Y., Rathert A., Loche P., Netz R.R.

    Journal of Chemical Physics   153 ( 3 )   2020年07月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    Solvent-implicit Monte Carlo (MC) simulations and mean-field theory are used to predict activity coefficients and excess interfacial tensions for NaF, NaCl, NaI, KF, KCl, and KI solutions in good agreement with experimental data over the entire experimentally available concentration range. The effective ionic diameters of the solvent-implicit simulation model are obtained by fits to experimental activity coefficient data. The experimental activity coefficients at high salt concentrations are only reproduced if the ion-specific concentration-dependent decrement of the dielectric constant is included. The dielectric-constant dependent contribution of the single-ion solvation free energy to the activity coefficient is significant and is included. To account for the ion-specific excess interfacial tension of salt solutions, in addition to non-ideal solution effects and the salt-concentration-dependent dielectric decrement, an ion-specific ion-interface interaction must be included. This ion-interface interaction, which acts in addition to the dielectric image-charge repulsion, is modeled as a box potential, is considerably more long-ranged than the ion radius, and is repulsive for all ions considered except iodide, in agreement with previous findings and arguments. By comparing different models that include or exclude bulk non-ideal solution behavior, dielectric decrement effects, and ion-interface interaction potentials, we demonstrate how bulk and interfacial ion-specific effects couple and partially compensate each other. Our MC simulations, which correctly include ionic correlations and interfacial dielectric image-charge repulsion, are used to determine effective ion-surface interaction potentials that can be used in a modified Poisson-Boltzmann theory.

    DOI: 10.1063/5.0016103

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85088323965&origin=inward

  • Nanomolar Surface-Active Charged Impurities Account for the Zeta Potential of Hydrophobic Surfaces 査読有り

    Uematsu Y., Bonthuis D.J., Netz R.R.

    Langmuir   36 ( 13 )   3645 - 3658   2020年04月

     詳細を見る

    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    The electrification of hydrophobic surfaces is an intensely debated subject in physical chemistry. We theoretically study the ζ potential of hydrophobic surfaces for varying pH and salt concentration by solving the Poisson-Boltzmann and Stokes equations with individual ionic adsorption affinities. Using the ionic surface affinities extracted from the experimentally measured surface tension of the air-electrolyte interface, we first show that the interfacial adsorption and repulsion of small inorganic ions such as H3O+, OH-, HCO3-, and CO32- cannot account for the ζ potential observed in experiments because the surface affinities of these ions are too small. Even if we take hydrodynamic slip into account, the characteristic dependence of the ζ potential on pH and salt concentration cannot be reproduced. Instead, to explain the sizable experimentally measured ζ potential of hydrophobic surfaces, we assume minute amounts of impurities in the water and include the impurities' acidic and basic reactions with water. We find good agreement between our predictions and the reported experimental ζ potential data of various hydrophobic surfaces if we account for impurities that consist of a mixture of weak acids (pKa = 5-7) and weak bases (pKb = 12) at a concentration of the order of 10-7 M.

    DOI: 10.1021/acs.langmuir.9b03795

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85083041833&origin=inward

  • Giant Axial Dielectric Response in Water-Fille Nanotubes an Effective Electrostatic Ion-Ion Interactions from a Tensorial Dielectric Moel 査読有り

    Loche P., Ayaz C., Schlaich A., Uematsu Y., Netz R.R.

    Journal of Physical Chemistry B   123 ( 50 )   10850 - 10857   2019年12月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    Molecular ynamics simulations in conjunction with effective meium theory are use to investigate ielectric effects in water-fille nanotubes. The resulting effective axial ielectric constant shows a ivergent increase for small nanotube raii that epens on the nanotube length, while the effective raial ielectric constant ecreases significantly for thin nanotubes. By solving Poisson's equation for an anisotropic ielectric meium in cylinrical geometry, we show that the axial ion-ion interaction epens for small separations primarily on the raial ielectric constant, not on the axial one. This means that electrostatic ion-ion interactions in thin water-fille nanotubes are on the linear ielectric level significantly enhance ue to water confinement effects at small separations, while at large separations the outsie meium ominates. If the outsie meium is metallic, then the ion-ion interaction ecays exponentially for large ion separation.

    DOI: 10.1021/acs.jpcb.9b09269

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85076524846&origin=inward

  • Impurity effects at hydrophobic surfaces 査読有り

    Uematsu Y., Bonthuis D.J., Netz R.R.

    Current Opinion in Electrochemistry   13   166 - 173   2019年02月

     詳細を見る

    担当区分:筆頭著者   記述言語:英語   掲載種別:記事・総説・解説・論説等(学術雑誌)

    The effective charge of hydrophobic surfaces and in particular of the air–water interface is a crucial parameter for electrochemistry, colloidal chemistry and interfacial science, but different experiments give conflicting estimates. Zeta-potential and disjoining-pressure measurements point to a strongly negative surface charge, often interpreted as being due to adsorbing hydroxide ions. In contrast, surface tension measurements of acids and bases suggest the hydronium ion to be surface active, in agreement with some surface-specific non-linear spectroscopy results. The air–electrolyte interfacial tension exhibits a characteristic minimum at millimolar electrolyte concentration for all salts, the so-called Jones–Ray effect, which points to competitive adsorption mechanisms present in dilute electrolyte solutions. We show that all these puzzling experimental findings can be explained by the presence of trace amounts of surface-active charged impurities, most likely anionic surfactants.

    DOI: 10.1016/j.coelec.2018.09.003

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85054430817&origin=inward

  • Intentionally Added Ionic Surfactants Induce Jones-Ray Effect at Air-Water Interface 査読有り

    Uematsu Y., Chida K., Matsubara H.

    Colloids and Interface Science Communications   27   45 - 48   2018年11月

     詳細を見る

    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    The Jones-Ray effect is an anomalous minimum in the surface tension of aqueous electrolytes at millimolar salt concentrations. We experimentally demonstrated that intentionally added ionic surfactants induce the Jones-Ray effect. The one-dimensional Poisson-Boltzmann theory, including the effect of surfactant adsorption and salt depletion, excellently agrees with the obtained experimental data. All the parameters of the ion-specific surface affinities used in the theory are consistent with previous experiments. These results strongly suggest that the Jones-Ray effect observed so far has been induced by the inevitable contamination of the air-water interfaces.

    DOI: 10.1016/j.colcom.2018.10.003

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85055020845&origin=inward

  • Linear response functions of an electrolyte solution in a uniform flow 査読有り

    Adar R., Uematsu Y., Komura S., Andelman D.

    Physical Review E   98 ( 3 )   2018年09月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    We study the steady-state response of a dilute monovalent electrolyte solution to an external source with a constant relative velocity with respect to the fluid. The source is taken as a combination of three perturbations: an external force acting on the fluid, an externally imposed ionic chemical potential, and an external charge density. The linear response functions are obtained analytically and can be decoupled into three independent terms, corresponding to (i) fluid flow and pressure, (ii) total ionic number density and current, and (iii) charge density, electrostatic potential, and electric current. It is shown how the uniform flow breaks the equilibrium radial symmetry of the response functions, leading to a distortion of the ionic cloud and electrostatic potential, which deviates from the standard Debye-Hückel result. The potential of a moving charge is underscreened in its direction of motion and overscreened in the opposite direction and normal plane. As a result, an unscreened dipolar electric field and electric currents are induced far from the charged source. We relate our general formalism to several experimental setups, such as colloidal sedimentation.

    DOI: 10.1103/PhysRevE.98.032604

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85053410485&origin=inward

  • Analytical Interfacial Layer Model for the Capacitance and Electrokinetics of Charged Aqueous Interfaces 査読有り

    Uematsu Y., Netz R., Bonthuis D.

    Langmuir   34 ( 31 )   9097 - 9113   2018年08月

     詳細を見る

    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    We construct an analytical model to account for the influence of the subnanometer-wide interfacial layer on the differential capacitance and the electro-osmotic mobility of solid-electrolyte interfaces. The interfacial layer is incorporated into the Poisson-Boltzmann and Stokes equations using a box model for the dielectric properties, the viscosity, and the ionic potential of mean force. We calculate the differential capacitance and the electro-osmotic mobility as a function of the surface charge density and the salt concentration, both with and without steric interactions between the ions. We compare the results from our theoretical model with experimental data on a variety of systems (graphite and metallic silver for capacitance and titanium oxide and silver iodide for electro-osmotic data). The differential capacitance of silver as a function of salinity and surface charge density is well reproduced by our theory, using either the width of the interfacial layer or the ionic potential of mean force as the only fitting parameter. The differential capacitance of graphite, however, needs an additional carbon capacitance to explain the experimental data. Our theory yields a power-law dependence of the electro-osmotic mobility on the surface charge density for high surface charges, reproducing the experimental data using both the interfacial parameters extracted from molecular dynamics simulations and fitted interfacial parameters. Finally, we examine different types of hydrodynamic boundary conditions for the power-law behavior of the electro-osmotic mobility, showing that a finite-viscosity layer explains the experimental data better than the usual hydrodynamic slip boundary condition. Our analytical model thus allows us to extract the properties of the subnanometer-wide interfacial layer by fitting to macroscopic experimental data.

    DOI: 10.1021/acs.langmuir.7b04171

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85051186983&origin=inward

  • Crossover of the Power-Law Exponent for Carbon Nanotube Conductivity as a Function of Salinity 査読有り

    Uematsu Y., Netz R.R., Bocquet L., Bonthuis D.J.

    Journal of Physical Chemistry B   122 ( 11 )   2992 - 2997   2018年03月

     詳細を見る

    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    On the basis of the Poisson-Boltzmann equation in cylindrical coordinates, we calculate the conductivity of a single charged nanotube filled with electrolyte. The conductivity as a function of the salt concentration follows a power-law, the exponent of which has been controversially discussed in the literature. We use the co-ion-exclusion approximation and obtain the crossover between different asymptotic power-law behaviors analytically. Numerically solving the full Poisson-Boltzmann equation, we also calculate the complete diagram of exponents as a function of the salt concentration and the pH for tubes with different radii and pKa values. We apply our theory to recent experimental results on carbon nanotubes using the pKa as a fit parameter. In good agreement with the experimental data, the theory shows power-law behavior with the exponents 1/3 at high pH and 1/2 at low pH, with a crossover depending on salt concentration, tube radius and pKa.

    DOI: 10.1021/acs.jpcb.8b01975

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85044269322&origin=inward

  • The effects of ion adsorption on the potential of zero charge and the differential capacitance of charged aqueous interfaces 査読有り

    Uematsu Y., Netz R.R., Bonthuis D.J.

    Journal of Physics Condensed Matter   30 ( 6 )   2018年01月

     詳細を見る

    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    Using a box profile approximation for the non-electrostatic surface adsorption potentials of anions and cations, we calculate the differential capacitance of aqueous electrolyte interfaces from a numerical solution of the Poisson-Boltzmann equation, including steric interactions between the ions and an inhomogeneous dielectric profile. Preferential adsorption of the positive (negative) ion shifts the minimum of the differential capacitance to positive (negative) surface potential values. The trends are similar for the potential of zero charge; however, the potential of zero charge does not correspond to the minimum of the differential capacitance in the case of asymmetric ion adsorption, contrary to the assumption commonly used to determine the potential of zero charge. Our model can be used to obtain more accurate estimates of ion adsorption properties from differential capacitance or electrocapillary measurements. Asymmetric ion adsorption also affects the relative heights of the characteristic maxima in the differential capacitance curves as a function of the surface potential, but even for strong adsorption potentials the effect is small, making it difficult to reliably determine the adsorption properties from the peak heights.

    DOI: 10.1088/1361-648X/aaa4d4

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85040936457&origin=inward

  • Charged Surface-Active Impurities at Nanomolar Concentration Induce Jones-Ray Effect 査読有り

    Uematsu Y., Bonthuis D., Netz R.

    Journal of Physical Chemistry Letters   9 ( 1 )   189 - 193   2018年01月

     詳細を見る

    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    The electrolyte surface tension exhibits a characteristic minimum around a salt concentration of 1 mM for all ion types, known as the Jones-Ray effect. We show that a consistent description of the experimental surface tension of salts, bases, and acids is possible by assuming charged impurities in the water with a surface affinity typical for surfactants. Comparison with experimental data yields an impurity concentration in the nanomolar range, well below the typical experimental detection limit. Our modeling reveals salt-screening enhanced impurity adsorption as the mechanism behind the Jones-Ray effect: for very low salt concentration added salt screens the electrostatic repulsion between impurities at the surface, which dramatically increases impurity adsorption and thereby reduces the surface tension.

    DOI: 10.1021/acs.jpclett.7b02960

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85040165991&origin=inward

  • Power-law electrokinetic behavior as a direct probe of effective surface viscosity 査読有り

    Uematsu Y., Netz R., Bonthuis D.

    Chemical Physics Letters   670   11 - 15   2017年01月

     詳細を見る

    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    An exact solution to the Poisson-Boltzmann and Stokes equations is derived to describe the electric double layer with inhomogeneous dielectric and viscosity profiles in a lateral electric field. In the limit of strongly charged surfaces and low salinity, the electrokinetic flow magnitude follows a power law as a function of the surface charge density. Remarkably, the power-law exponent is determined by the interfacial dielectric constant and viscosity, the latter of which has eluded experimental determination. Our approach provides a novel method to extract the effective interfacial viscosity from standard electrokinetic experiments. We find good agreement between our theory and experimental data.

    DOI: 10.1016/j.cplett.2016.12.056

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85008428516&origin=inward

  • Interfacial layer effects on surface capacitances and electro-osmosis in electrolytes 査読有り

    Bonthuis D., Uematsu Y., Netz R.

    Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences   374 ( 2060 )   2016年02月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)

    Many properties of the interfacial layer of water at surfaces differ significantly from those of bulk water. The consequences are most significant for the doublelayer capacitance and the electrokinetic properties. We model the interfacial hydration layer by a modified dielectric constant and a modified local viscosity over a single interfacial width. Analytic expressions in the low-charge Debye-Hückel approximation are derived and shown to describe experimental surface capacitance and electro-osmotic data in a unified framework.

    DOI: 10.1098/rsta.2015.0033

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84956631204&origin=inward

  • Nonlinear electro-osmosis of dilute non-adsorbing polymer solutions with low ionic strength 査読有り

    Uematsu Y.

    Soft Matter   11 ( 37 )   7402 - 7411   2015年08月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    Nonlinear electro-osmotic behaviour of dilute non-adsorbing polymer solutions with low salinity is investigated using Brownian dynamics simulations and a kinetic theory. In the Brownian simulations, the hydrodynamic interaction between the polymers and a no-slip wall is considered using the Rotne-Prager approximation of the Blake tensor. In a plug flow under a sufficiently strong applied electric field, the polymer migrates toward the bulk, forming a depletion layer thicker than the equilibrium one. Consequently, the electro-osmotic mobility increases nonlinearly with increasing electric field and becomes saturated. This nonlinear mobility does not depend qualitatively on the details of the rheological properties of the polymer solution. Analytical calculations using the kinetic theory for the same system quantitatively reproduce the results of the Brownian dynamics simulation well.

    DOI: 10.1039/c5sm01507c

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84942156427&origin=inward

  • Electrophoresis of electrically neutral porous spheres induced by selective affinity of ions 査読有り

    Uematsu Y.

    Physical Review E - Statistical, Nonlinear, and Soft Matter Physics   91 ( 2 )   2015年02月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    I investigate the possibility that electrically neutral porous spheres electrophorese in electrolyte solutions with asymmetric affinity of ions to spheres on the basis of electrohydrodynamics and the Poisson-Boltzmann and Debye-Bueche-Brinkman theories. Assuming a weak electric field and ignoring the double-layer polarization, I obtain analytical expressions for electrostatic potential, electrophoretic mobility, and flow field. In the equilibrium state, the Galvani potential forms across the interface of the spheres. Under a weak electric field, the spheres show finite mobility with the same sign as the Galvani potential. When the radius of the spheres is significantly larger than the Debye and hydrodynamic screening length, the mobility monotonically increases with increasing salinity.

    DOI: 10.1103/PhysRevE.91.022303

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84922537670&origin=inward

  • Electro-osmotic flow of semidilute polyelectrolyte solutions 査読有り

    Uematsu Y., Araki T.

    Journal of Chemical Physics   139 ( 9 )   2013年09月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    We investigate electro-osmosis in aqueous solutions of polyelectrolytes using mean-field equations. A solution of positively charged polyelectrolytes is confined between two negatively charged planar surfaces, and an electric field is applied parallel to the surfaces. When electrostatic attraction between the polymer and the surface is strong, the polymers adhere to the surface, forming a highly viscous adsorption layer that greatly suppresses the electro-osmosis. Conversely, electro-osmosis is enhanced by depleting the polymers from the surfaces. We also found that the electro-osmotic flow is invertible when the electrostatic potential decays to its bulk value with the opposite sign. These behaviors are well explained by a simple mathematical form of the electro-osmotic coefficient. © 2013 AIP Publishing LLC.

    DOI: 10.1063/1.4820236

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84903370885&origin=inward

  • Effects of strongly selective additives on volume phase transition in gels 査読有り

    Uematsu Y., Araki T.

    Journal of Chemical Physics   137 ( 2 )   2012年07月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)

    We investigate volume phase transition in gels immersed in mixture solvents, on the basis of a three-component Flory-Rehner theory. When the selectivity of the minority solvent component to the polymer network is strong, the gel tends to shrink with an increasing concentration of the additive, regardless of whether it is good or poor. This behavior originates from the difference of the additive concentration between inside and outside the gel. We also found the gap of the gel volume at the transition point can be controlled by adding the strongly selective solutes. By dissolving a strongly poor additive, for instance, the discontinuous volume phase transition can be extinguished. Furthermore, we observed that another volume phase transition occurs far from the original transition point. These behaviors can be well explained by a simplified theory neglecting the nonlinearity of the additive concentration. © 2012 American Institute of Physics.

    DOI: 10.1063/1.4732857

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84863910142&origin=inward

▼全件表示

著書

口頭発表・ポスター発表等

  • Ostwald ripening of aqueous microbubble solutions

    Yuki Uematsu

    Mini-symposium on Liquids 2023 

     詳細を見る

    開催期間: 2023年06月10日   記述言語:英語  

  • Analytic theory of nonlinearly coupled electrokinetics in nanochannels

    Yuki Uematsu

    ISBEC2023 

     詳細を見る

    開催期間: 2023年03月09日 - 2023年03月10日   記述言語:英語  

  • Electrification of water droplets released into the gas phase

    Ryota Shioya, Yuki Uematsu

    ISBEC2023 

     詳細を見る

    開催期間: 2023年03月09日 - 2023年03月10日   記述言語:英語  

  • 水-有機溶媒混合系における電気二重層容量測定

    岩崎暖人、木村康之、植松祐輝

    第10回ソフトマター研究会 

     詳細を見る

    開催期間: 2022年11月22日   記述言語:英語  

  • 水-1-プロパノール混合系における電気二重層容量測定

    岩崎暖人、木村康之、植松祐輝

    第73回コロイド界面討論会 

     詳細を見る

    開催期間: 2022年09月20日   記述言語:日本語  

  • 水-有機溶媒混合系における電気二重層容量測定

    岩崎暖人、木村康之、植松祐輝

    15th mini symposium on liquids 

     詳細を見る

    開催期間: 2022年07月09日   記述言語:英語  

▼全件表示

講演

  • 溶液界面の化学物理と流体力学の研究

    日本物理学会2023年春季大会 若手奨励賞受賞講演  2023年03月 

     詳細を見る

    発表言語:日本語   講演種別:招待講演  

  • Electrophoretic mobility of a water-in-oil droplet separately affected by the net charge and surface charge density

    ICPAC Kota Kinabalu  2022年11月 

     詳細を見る

    発表言語:英語   講演種別:招待講演  

  • Water-in-Oil型液滴の電気泳動移動度の決定因子

    第34回散乱研究会  2022年11月 

     詳細を見る

    発表言語:日本語   講演種別:招待講演  

報道関係

  • Law of growth and shrinkage of individual bubbles — Key to understanding nanobubble stability   インターネットメディア

    植松祐輝

    Science Japan  2023年04月25日

     詳細を見る

    執筆者:本人  

  • 发现气泡遵循的尺寸变化规律,成为阐明纳米气泡稳定性的关键   インターネットメディア

    植松祐輝

    客観日本  2023年03月29日

     詳細を見る

    執筆者:本人  

  • 個々の気泡が従うサイズ変化の法則   会誌・広報誌

    植松祐輝

    日本科学技術振興機構  2023年03月01日

     詳細を見る

    執筆者:本人  

  • 個々のマイクロバブルが従うサイズ変化の法則を解明   その他

    植松祐輝

    九州工業大学  2022年12月28日

     詳細を見る

    執筆者:本人  

学術関係受賞

  • 第17回 日本物理学会若手奨励賞(領域12)

    日本物理学会   2022年10月

    植松祐輝

     詳細を見る

    受賞国:日本国

担当授業科目(学内)

  • 2023年度   界面物理化学特論BP

  • 2023年度   界面物理化学特論EP

  • 2023年度   統計力学

  • 2023年度   情報工学基礎実験

  • 2022年度   統計力学

  • 2022年度   熱力学(P)

  • 2022年度   物理情報セミナー(3Q)

     詳細を見る

    科目区分:学部専門科目

▼全件表示

FD活動への参加

  • 2023年07月   全学FD研修

  • 2023年03月   新任FD3月研修会

  • 2023年02月   全学FD研修

  • 2023年01月   新任FD1月研修会

  • 2023年01月   全学FD研修

  • 2022年12月   新任FD12月研修会

  • 2022年11月   新任FD11月研修会

  • 2022年10月   情報工学研究院FD研修

  • 2022年09月   教養教育院FD

  • 2022年07月   情報工学研究院FD研修

  • 2022年07月   全学FD研修

  • 2022年06月   新任FD6月研修会

  • 2022年05月   新任FD5月研修会

▼全件表示

学会・委員会等活動

  • 日本物理学会   領域12運営委員  

    2022年04月 - 2023年03月

  • 界面動電現象研究会   役員  

    2020年04月 - 現在