2026/08/20 更新

ジャックリーン リーゼ
Lease Jacqueline
Lease Jacqueline
Scopus 論文情報
総論文数: 27 総Citation: 378 h-index: 14

棒グラフ及び折れ線グラフは最大で直近20年分が表示されます。

所属
研究本部 重点プロジェクトセンター グリーンマテリアル研究センター
職名
助教

研究キーワード

  • 複合材料

  • グリーンケミストリー

  • バイオマス

  • セルロース

研究分野

  • ナノテク・材料 / 高分子化学

  • ナノテク・材料 / 高分子材料

  • ナノテク・材料 / 有機機能材料

  • ナノテク・材料 / 有機合成化学

取得学位

  • 九州工業大学  -  博士(学術)   2025年03月

学内職務経歴

  • 2025年04月 - 現在   九州工業大学   研究本部   重点プロジェクトセンター   グリーンマテリアル研究センター     助教

所属学会・委員会

  •   公益社団法人 グリーンケミストリー研究会   日本国

  •   セルロース学会   日本国

  •   公益社団法人 高分子学会   日本国

論文

  • Optimization of mechanochemical reactions through cellulose transacylation with vinyl laurate 査読有り 国際誌

    Lease J., Tan P.Q., Ng K.X., Farid M.A.A., Andou Y.

    Polymer Journal   58 ( 6 )   647 - 658   2026年06月

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    担当区分:筆頭著者, 最終著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    Cellulose esters with long-chain alkyl groups are promising sustainable materials because their hydrophobicity and thermal stability can be tuned through chemical modification. We report a mechanochemical transacylation method for synthesizing cellulose laurates using vinyl laurate in a dimethyl sulfoxide/sodium hydroxide medium. The process enables the efficient modification of 0.81 g of cellulose and yields products with degrees of substitution ranging from 0.50 to 2.94 under different designated conditions. Structural analysis by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) confirmed successful esterification and reduced crystallinity. The physical properties varied systematically with substitution level, with higher substitution improving thermal stability and reducing wettability, providing opportunities to tailor performance. Response surface methodology, which is based on a five-level, four-factor central composite rotatable design, was applied to study the interactive effects of synthesis parameters and optimize the degree of substitution. The experimental results closely matched the predicted values with 97.3% accuracy, demonstrating the robustness of the approach. This study establishes a green and reproducible route for producing functional cellulose esters with potential applications in bioplastics.

    DOI: 10.1038/s41428-026-01152-x

    Scopus

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  • Aromatic Ester Bioplastics from Wood and Cellulose: Cinnamates as Greener Alternatives to Benzoates 査読有り 国際誌

    Froment L., Lease J., Sejati P.S., Akong F.O., Charbonnier C.G., Andou Y., Gérardin P.

    Materials   19 ( 3 )   2026年02月

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    担当区分:最終著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    Highlights: What are the main findings? Lignocellulose benzoates and cinnamates are thermoplastic. The pine esters had better properties than the MCC esters. The cinnamates had improved properties compared to benzoates. What are the implications of the main findings? Wood cinnamate esters are a superior alternative to cellulose benzoates. These materials could potentially be used as bioplastics for packaging. To address the environmental impact of petroleum-derived plastics, lignocellulose esters provide a promising renewable alternative. However, research has primarily focused on linear cellulose esters, leaving raw biomass aromatic derivatives largely overlooked. Herein, we report a one-pot, room-temperature synthesis of cinnamate and benzoate esters from microcrystalline cellulose (MCC) and raw pine sawdust. A breakthrough finding reveals that pine esters consistently outperform pure MCC, achieving tensile strengths of 5–8 MPa (vs. 1–3 MPa for MCC) possibly due to a lignin-driven synergistic effect facilitating π–π stacking. The resulting films are hydrophobic (contact angles 80–100°) and fully thermoplastic. Cinnamates emerge as a technically superior and “greener” alternative to benzoates, paving the way for the direct upcycling of wood waste into sustainable packaging materials within a circular economy.

    DOI: 10.3390/ma19030574

    Scopus

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  • Effect of Unsaturation on Thermoplastic Lignocellulosic Fatty Acid Ester Properties 査読有り 国際誌

    Froment L., Lease J., Sejati P.S., Gérardin-Charbonnier C., Akong F.O., Andou Y., Gérardin P.

    Journal of Applied Polymer Science   2026年01月

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    担当区分:最終著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    Fatty acid esters of lignocellulose are emerging as potential sustainable bio-based alternatives to fossil plastics. However, most studies focus on cellulose and saturated fatty acids; those made using lignocellulose or unsaturated acids are receiving considerably less attention. This study explores pine sawdust and microcrystalline cellulose (MCC) after modification with 3 commonly available unsaturated acids: oleic (octadecenoic, C18:1), linoleic (octadecadienoic, C18:2), and sorbic (2,4-hexadienoic, C6:2) acids. The six resulting bioplastics are extensively characterized using FTIR, XRD, and solid-state <sup>13</sup>C NMR for the chemical structure and crystallinity, TGA, DSC, and TMA for the thermal properties, SEM and water contact angles (WCAs) for surface analysis and tensile testing for the mechanical properties. There are only small differences between the oleate and linoleate esters, which have properties similar to previously described cellulose stearate (decaoctanoate) esters, as well as tensile strengths or elongation at break values comparable to some forms of conventional fossil plastics and bioplastics. The sorbate esters, however, have inferior properties. This study demonstrates that thermoplastic materials can be derived from unsaturated fatty acids, which are readily obtained from plants and either sawdust or cellulose.

    DOI: 10.1002/app.71084

    Scopus

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  • Synthesis of Nanocellulose Derivatives through Esterification with Naphthoic Acid as a Fluorescent Additive 査読有り 国際誌

    Lease J., Sahin Z.M., A Farid M.A., Andou Y.

    ACS Sustainable Chemistry and Engineering   12 ( 31 )   11789 - 11796   2024年08月

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    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    The demand for sustainable and renewable resources has significantly increased in recent decades. Cellulose, as a potential and abundant resource in industry, offers promising prospects. As a biological polymer primarily originating from lignocellulosic biomass, cellulose is biodegradable and recyclable, making it an attractive candidate for mitigating environmental issues. In this research, microcrystalline cellulose (MCC) and cellulose nanofibers (CNFs) are modified using 1-naphthoic acid (1-NA) through an esterification reaction in a tosyl chloride/pyridine solvent system to produce fluorophore-labeled cellulose. Various characterization methods such as Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, and X-ray diffraction (XRD) are used to investigate the success of the modification reaction. Cellulose modification results in a decrease in the thermal stability of cellulose by lowering the degradation temperature. The glass-transition temperature (T<inf>g</inf>) is observed after inducing the naphthoate side chain, which is around 160 °C. The cellulose naphthoate exhibits strong ultraviolet (UV) absorption peaks at around 282 nm and presents good fluorescence properties. Herein, it can be used in fluorescence coatings, sensors, and also packaging.

    DOI: 10.1021/acssuschemeng.4c04206

    Scopus

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  • Effect of cellulose materials on the mechanochemical-assisted reaction system with oleic acid 査読有り 国際誌

    Lease J., Kawano T., Andou Y.

    Rsc Advances   13 ( 39 )   27558 - 27567   2023年09月

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    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    As the most abundant natural polymer in nature, cellulose has become the promising alternative raw material to replace fossil-based polymer. Owing to the presence of innumerable hydroxyl groups, various approaches are employed to render processability of cellulose. Herein, a sustainable esterification strategy, mechanochemical-assisted esterification, was developed to produce cellulose oleate (CO) with only a small amount of solvent. The differences in reactivity between all types of cellulose were elucidated. According to thermal stability analysis, the degradation temperature decreased after modification due to the substitution of the long oleoyl group. High degree of substitution (DS) of CO also possessed glass transition temperature (T<inf>g</inf>) based on differential scanning calorimetry (DSC) analysis. Herewith, the processability of cellulose was introduced after modification. In this study, bamboo waste cellulose nanofiber oleate (BW CNF-OA) showed the highest DS (2.28) among the COs. Its higher surface reactivity due to the high surface aspect ratio led to a higher quantity of fatty acids attached to the cellulose. For the mechanical properties, low DS of COs exhibited higher tensile strength values. In a nutshell, this greener approach is more favorable than conventional chemical esterification in terms of reduced solvent dosage and improved sustainability.

    DOI: 10.1039/d3ra04715f

    Scopus

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  • Facile Preparation of Cellulose Fiber Reinforced Polypropylene Using Hybrid Filler Method 査読有り 国際誌

    Mustapha S., Lease J., Eksiler K., Sim S.T., Ariffin H., Andou Y.

    Polymers   14 ( 8 )   2022年04月

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    担当区分:最終著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    Dried hybrid fillers comprised of silica/CNF were successfully synthesized in ethanol/water mixed solvents at room temperature without the usage of any precursor. The as-prepared fillers were incorporated with polypropylene (PP) as a polymer matrix through a twin-screw extruder. From surface morphology analysis, the agglomeration of the silica/CNF hybrid fillers was prevented in the PP matrix and they exhibited moderate transparency, around 17.9% and 44.6% T at 660 nm. Further, the chemical structures of the polymer composites were identified by Fourier transform infrared (FT-IR) analysis. According to thermogravimetric analysis (TGA), the insertion of silica as a co-filler to the PP matrix resulted in an increase in its degradation onset temperature and also thermal stability. In addition, the mechanical properties of the PP composites also increased after the blending process with the hybrid fillers. Overall, sample PP-SS/CNF exhibited the highest tensile strength, which was 36.8 MPa, or around 73.55% compared to the pristine PP. The improvements in tensile strength were attributed to good dispersion and enhanced efficiency of the stress transfer mechanism between the silica and the cellulose within the PP matrix. However, elongation of the sample was reduced sharply due to the stiffening effect of the filler.

    DOI: 10.3390/polym14081630

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  • Esterification of cellulose with long fatty acid chain through mechanochemical method 査読有り 国際誌

    Lease J., Kawano T., Andou Y.

    Polymers   13 ( 24 )   2021年12月

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    担当区分:筆頭著者, 最終著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    Mechanochemical reaction, a green synthetic esterification route was utilized to prepare long-chain cellulose esters from microcrystalline cellulose. The influence of reaction conditions such as reaction temperature and time were elucidated. Only low dosage of oleic acid, 1-butyl-3-metylimidazolium acetate, and p-toluenesulfonyl chloride were required. The success of modification reaction was confirmed by Fourier transforms infrared spectroscopy as a new absorbance peak at 1731 cm<sup>−1</sup> was observed, which indicated the formation of carbonyl group (C=O). Solid-state nuclear magnetic resonance was also performed to determine the structural property and degree of substitution (DS) of the cellulose oleate. Based on the results, increasing reaction temperature and reaction time promoted the esterification reaction and DS. DS values of cellulose oleates slightly decreased after 12 h reaction time. Besides, X-ray diffraction analysis showed the broadening of the diffraction peaks and thermal stability decreased after esterification. Hence, the findings suggested that grafting of oleic acid’s aliphatic chain onto the cellulose backbone lowered the crystallinity and thermal stability.

    DOI: 10.3390/polym13244397

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  • Monoamine-induced supramolecular gelation of cellulose succinate via ionic complexation 査読有り 国際誌

    Chandran B., Lease J., Ruozhu W., Andou Y.

    Chemistry Letters   55 ( 7 )   2026年07月

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    担当区分:最終著者   記述言語:英語   掲載種別:記事・総説・解説・論説等(その他)

    Cellulose succinate (CS), an anionic cellulose ester, was examined as a semi-rigid polysaccharide platform for supramolecular gelation with monoamines, typically regarded as simple counterions rather than crosslinkers. Near-stoichiometric conditions at 50 °C yielded self-supporting hydrogels within 15 to 18 h. FTIR shifts and zeta-potential changes support ammonium–carboxylate ion pairing and partial charge compensation. Reversible vapor-phase ethylamine uptake, approximately 6.5-fold higher than cellulose, indicates solid-state acid–base interaction. These findings suggest that cooperative ionic complexation and secondary interactions collectively promote monoamine-induced gelation.

    DOI: 10.1093/chemle/upag136

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  • Cellulose Succinate as a Bio-Based Anionic Polyelectrolyte: Charge-Driven Gelation and Electrostatic Complexation with Aliphatic Diamines 査読有り 国際誌

    Bharath Chandran, Jacqueline Lease, Yoshito Andou

    Applied Polymer Materials ( American Chemical Society )   8 ( 13 )   10449 - 10460   2026年05月

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    担当区分:最終著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    DOI: 10.1021/acsapm.6c01380

  • Duckweed-derived magnetic adsorbent for efficient removal of methylene blue 査読有り 国際誌

    Seng K.W.K., Zheng A.L.T., Jeffrey K.B., Hii T.T., Chung E.L.T., Lease J., Andou Y.

    Biomass Conversion and Biorefinery   16 ( 3 )   2026年02月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    Low-cost and easily recoverable adsorbents are urgently needed for efficient treatment of dye-contaminated wastewater. In this study, a green magnetic duckweed-derived adsorbent (MDW) was synthesized via co-precipitation of Fe<inf>3</inf>O<inf>4</inf> nanoparticles (NPs) onto dried duckweed using ascorbic acid (AA) as a reducing agent. The MDW exhibited a maximum methylene blue (MB) adsorption capacity of 78.59 mg/g under optimal conditions of pH 10, 50 mg/L initial MB concentration, 10 mg adsorbent dosage, and 60 min contact time, achieving a removal efficiency of 85.27%. Kinetic analysis showed that adsorption followed the pseudo-second-order (PSO) model (R² > 0.999), while equilibrium data were best described by the Temkin isotherm model, indicating heterogeneous surface interactions. Thermodynamic analysis revealed an exothermic and spontaneous process with negative ΔG° values across the temperature range of 298–318 K. The MDW retained over 69% of its initial removal efficiency after five regeneration cycles, confirming good reusability. Cost analysis estimated the synthesis cost at approximately RM 29.51/kg, highlighting economic feasibility. These findings demonstrate that MDW is a sustainable, low-cost, and magnetically recoverable adsorbent with strong potential for scalable wastewater treatment applications.

    DOI: 10.1007/s13399-025-06946-2

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  • Assessing the Photocatalytic Performance of Hydrothermally Synthesized Fe-Doped BiVO4 Under Low-Intensity UV Irradiation 査読有り 国際誌

    Maran M.A., Zheng A.L.T., Tan H.Y., Sarbini S.R., Tan K.B., Boonyuen S., Wong K.K.S., Chung E.L.T., Lease J., Andou Y.

    Arabian Journal for Science and Engineering   51 ( 2 )   1689 - 1707   2026年01月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    This study demonstrates the potential of Fe-doped BiVO<inf>4</inf> as an efficient photocatalyst for the degradation of tetracycline (TC). The Fe-doped BiVO<inf>4</inf> was synthesized using the hydrothermal method, resulting in a monoclinic heterostructure with a crystallite size ranging from 27.37 to 29.10 nm and an optical band gap of 2.69–2.87 eV. Photocatalytic tests revealed that 3 wt% Fe doping exhibited the highest degradation efficiency, removing 73.37% of TC in 120 min under a low-power (13 W) UV lamp. The enhanced photocatalytic performance was attributed to the improved electron–hole separation and optimized Fe doping concentration, which facilitated more efficient light absorption and charge carrier dynamics. Additionally, antibacterial tests confirmed the catalyst’s ability to inactivate Staphylococcus aureus, even in the absence of light, demonstrating its dual functionality in both pollutant degradation and bacterial inactivation. The cost analysis revealed that the synthesized Fe-doped BiVO<inf>4</inf> costs RM 8.17 per gram, further enhancing its appeal for scalable and cost-effective applications. These findings highlight the versatility of Fe-doped BiVO<inf>4</inf> as a photocatalyst for addressing antibiotic-based pollution and waterborne pathogens, making it a promising candidate for practical applications in wastewater treatment and environmental remediation. These findings contribute to global efforts in mitigating waterborne antibiotic and microbial pollution, particularly in regions where access to high-energy treatment technologies is limited.

    DOI: 10.1007/s13369-025-10278-8

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  • ZIF-8/graphene composite for photocatalytic degradation under low intensity UV irradiation and antibacterial applications 査読有り 国際誌

    Manivel C.M., Zheng A.L.T., Kannan R., Seenivasagam S., Yun Hin T.Y., Boonyuen S., Lease J., Andou Y., Tan K.B.

    Scientific Reports   15 ( 1 )   2025年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    In this study, we synthesized a ZIF-8/graphene (Gr) composite and evaluated its photocatalytic degradation performance toward levofloxacin (LVX) under low-intensity UV light. The composite exhibited improved charge separation and enhanced reactive oxygen species (·OH, ·O<inf>2</inf><sup>−</sup>, h<sup>+</sup>) generation compared to its individual components. Under optimal conditions (20 mg catalyst, 5 mg/L LVX, neutral pH), a 25.70% degradation was achieved after 120 min of irradiation, following pseudo-first-order (PFO) kinetics. While the degradation efficiency was modest, the catalyst operated effectively under low-energy conditions and demonstrated selective antibacterial activity against E. coli in dark conditions. These findings suggest that ZIF-8/Gr composites hold promise as dual-functional materials for pollutant mitigation and microbial control in niche wastewater applications, particularly where energy availability is limited. Further work is needed to enhance degradation efficiency and assess long-term operational stability.

    DOI: 10.1038/s41598-025-07444-1

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  • Dual Role of Pennisetum purpureum as a Phytogenic Feed Additive: Enhancing Growth and Profitability in Antibiotic-Free Broiler Production 査読有り 国際誌

    Zheng A.L.T., Wong K.K.S., Ong Y.L., Lease J., Andou Y., Jesse F.F.A., Chung E.L.T.

    Bioresources   20 ( 4 )   8654 - 8673   2025年11月

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    掲載種別:研究論文(学術雑誌)

    Amid growing concerns about antibiotic resistance in livestock systems, there is a global shift toward identifying plant-based alternatives to conventional synthetic feed additives. This study explored the physicochemical characteristics of raw Napier grass (Pennisetum purpureum) and assessed its viability as a low-cost, functional feed additive for colored broiler chicken diets. Comprehensive characterization was conducted on the raw grass, revealing structural features and functional groups characteristic of bioactive, fibrous biomass. A subsequent feeding trial was conducted with 216 Sasso broiler chicks divided among six dietary regimens: a negative control (basal diet), a positive control (100 mg/kg oxytetracycline), and four supplementation levels of P. purpureum grass meal (1.25 to 5.00 g/kg). The highest supplementation level (5.00 g/kg) significantly enhanced growth performance (p < 0.05), reducing feed conversion ratio (FCR) while maintaining low feed intake. Economic analyses demonstrated that this treatment yielded the greatest profitability, exhibiting superior net profit margin, break-even efficiency, and margin of safety. These findings indicated P. purpureum as a promising phytogenic feed additive with dual benefits of enhancing production efficiency and promoting sustainable poultry farming.

    DOI: 10.15376/biores.20.4.8654-8673

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  • Sustainable dye wastewater treatment: utilizing duckweed-derived adsorbents for efficient methylene blue removal 査読有り 国際誌

    Jeffrey K.B., Zheng A.L.T., Hii T.T., Seng K.W.K., Chung E.L.T., Lease J., Andou Y.

    Biomass Conversion and Biorefinery   15 ( 12 )   19157 - 19173   2025年06月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    Invasive plants threaten natural ecosystems due to their rapid spread and growth. This study used duckweed (DW) to develop a low-cost and sustainable adsorbent to remove methylene blue (MB) from aqueous solution. The adsorbent was analysed using various techniques. Fourier transform infrared spectroscopy (FT-IR) identified oxygen-containing functional groups on the DW surface that enhanced its adsorption capacity. Optimal adsorption conditions were achieved with an adsorbent amount of 20 mg, a pH of 10, and an initial MB concentration of 10 mg/L. Experimental data matched the pseudo-second-order (PSO) model across all concentrations, including 10 mg/L (Q<inf>e</inf> = 73.53 mg/g), 20 mg/L (Q<inf>e</inf> = 183.15 mg/g), and 50 mg/L (Q<inf>e</inf> = 200.80 mg/g). The Temkin isotherm model fit the data better than the Langmuir and Freundlich models. Adsorption decreased with increasing temperatures (ΔG<sup>o</sup> = − 7.56 to − 8.06 kJ/mol, ΔH<sup>o</sup> = − 4.93 kJ/mol, ΔS<sup>o</sup> = − 6.76 kJ/mol). The primary adsorption mechanisms included electrostatic interactions, hydrogen bonding, and π-π electron interactions. The production cost of the DW adsorbent was estimated at RM 14.40 per kg, making it a more affordable alternative. With its high adsorption capacity and wide availability, DW is a promising material for controlling dye pollution in wastewater.

    DOI: 10.1007/s13399-024-06432-1

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  • Temperature-dependent deoxygenation during sulfonation for graphene oxide reduction 査読有り 国際誌

    Ahmad Farid M.A., Lease J., Andou Y.

    Applied Surface Science   691   2025年05月

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    担当区分:最終著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    The objective of this study was to elucidate the sulfonation behaviour of graphene oxide (GO) across a temperature range of 50 °C, 100 °C, and 150 °C under a nitrogen atmosphere. Analysis revealed a significant reduction in –OH, C-O, and O-C-O functional groups, facilitating a substantial conversion from sp<sup>3</sup> to sp<sup>2</sup> carbon hybridization. Specifically, the sp<sup>2</sup> carbon content increased from 37.43 ± 2.0 % in GO to 50.32 ± 2.5 % in GO-SO<inf>3</inf>H50, 43.72 ± 3.0 % in GO-SO<inf>3</inf>H100, and 47.92 ± 2.8 % in GO-SO<inf>3</inf>H150. At higher temperatures, deoxygenation led to a decrease in C-S density due to the pronounced removal of oxygen moieties, which constrained the availability of functional groups for −SO<inf>3</inf>H binding. SEM imaging corroborated that sulfonated GO retained its disordered stacked layer configuration, consistent with the precursor. These results affirm that sulfonation is a viable alternative for synthesizing reduced graphene oxide (rGO), with enhanced sp<sup>2</sup> carbon content and modified structural characteristics.

    DOI: 10.1016/j.apsusc.2025.162678

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  • Rare earth elements for enhancing photocatalysis in pollutant degradation and water treatment 査読有り 国際誌

    Zheng A.L.T., Sinin A.E., Jin W.T., Feng K.L., Boonyuen S., Chung E.L.T., Lease J., Andou Y.

    International Journal of Environmental Science and Technology   22 ( 8 )   7247 - 7270   2025年04月

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    記述言語:英語   掲載種別:記事・総説・解説・論説等(学術雑誌)

    This review examines recent progress in using rare earth-based photocatalysts and their composites to degrade environmental pollutants. Rare earth elements (REEs), recognized for their unique electronic configurations and exceptional optical properties, have become effective dopants and co-catalysts, enhancing the capabilities of traditional semiconductor photocatalysts. Key enhancement strategies, including doping, co-doping, surface functionalization, and heterostructure formation, are analyzed to illustrate how they improve photocatalytic efficiency, stability, and selectivity. The review details studies on the photocatalytic degradation of various pollutants, such as dyes, antibiotics, and pesticides. It highlights how REEs contribute to better light absorption, efficient charge separation, and increased reactive oxygen species (ROS) production. The review also addresses challenges with the long-term stability of doped photocatalysts, like structural degradation and dopant leaching, suggesting possible solutions to enhance durability. By providing a broad overview, this review aims to guide researchers in designing next-generation photocatalysts for environmental remediation and to support the development of more sustainable water treatment technologies. Additionally, emerging trends such as green synthesis, integration with carbon-based nanocomposites, and scalable photocatalytic applications stressed REEs’ potential in advancing eco-friendly water treatment solutions, aligning with global sustainability objectives.

    DOI: 10.1007/s13762-024-06203-5

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  • Physicochemical Properties and Cost-Benefit of Supplementing Signal Grass (Brachiaria decumbens) in Sasso Broilers Production 査読有り 国際誌

    Seng K.W.K., Zheng A.L.T., Ong Y.L., Lease J., Andou Y., Jesse F.F.A., Dunshea F.R., Chung E.L.T.

    Bioresources   20 ( 2 )   3176 - 3194   2025年01月

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    記述言語:英語   掲載種別:記事・総説・解説・論説等(学術雑誌)

    There has been a growing interest in using natural alternatives to synthetic additives in animal feed. This study aimed to examine the physicochemical properties of signal grass (Brachiaria decumbens) and its cost-benefit application in broiler production. The characterization was performed using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric/derivative thermogravimetry (TG/DTG), and scanning electron microscopy (SEM). A feeding trial involving 216 Sasso broiler chicks was conducted to assess the economic value of including B. decumbens grass meal in their diets. The chicks were divided into six groups, with Treatments 1 and 2 serving as controls (without antibiotics and with oxytetracycline, respectively). Treatments 3 to 6 received diets supplemented with 1.25, 2.50, 3.75, and 5.00 g/kg of B. decumbens grass meal without antibiotics. Body weight and feed intake were monitored over eight weeks to determine growth performance and feed conversion ratio. Broilers in Treatment 6, which received 5.00 g/kg of the grass meal, showed significantly improved growth (p < 0.05). A cost-benefit analysis revealed that T6 was the most profitable, suggesting B. decumbens' potential as an effective feed additive for broilers.

    DOI: 10.15376/biores.20.2.3176-3194

    Scopus

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  • Behaviour and mechanics of phenolic sorption by novel bio-based graphene derivatives as adsorbents 査読有り

    Ahmad Farid M.A., Lease J., Andou Y.

    Chemosphere   366   2024年10月

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    担当区分:最終著者   記述言語:英語   掲載種別:研究論文(学術雑誌)

    Phenolic compounds, notorious for their environmental and health hazards, demand efficient removal from wastewater. Our research leads in synthesizing bio-based graphene derivatives from biomass-derived lignin, such as graphene oxide (bGO) and reduced graphene oxide (brGO), and these materials show promise in effectively removing hydrophobic pollutants like phenol and tannic acid. Hence, this study investigated the mechanical and dynamical aspects of their sorptions by bGO and brGO. Both adsorbents demonstrated a comparable adsorption pattern, with enhanced efficiency observed at higher adsorbent dosage, prolonged contact time, neutralized pH solutions, and elevated temperatures. Of note, phenol is removed at a much greater rate (>94%) than tannic acid (>84%) by both adsorbents at a dosage of 180 mg L<sup>−1</sup>, pH 6.5, 900 min, and 25 °C. The Freundlich model provided the best fit for the isotherm data of both phenol (R<sup>2</sup> = 0.99) and tannic acid (R<sup>2</sup> = 0.98), while the pseudo-second-order model effectively described the adsorption kinetics of phenol (R<sup>2</sup> = 0.99) and tannic acid (R<sup>2</sup> = 0.99). The determined activation energy exceeds 5.88 kJ mol<sup>−1</sup>, affirming the prevalence of physisorption as the dominant mechanism in the adsorption process. Thermodynamic analysis confirmed that the adsorption process is endothermic (ΔH) and occurs spontaneously (ΔG), indicating a random (ΔS) nature. However, the percentage removal plunged considerably after five consecutive adsorption-desorption cycles, attributed to the alterations of active sites on bGO and brGO.

    DOI: 10.1016/j.chemosphere.2024.143490

    Scopus

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  • Nanostructures embedded on porous materials for the catalytic reduction of nitrophenols: a concise review 査読有り 国際誌

    Zheng A.L.T., Teo E.Y.L., Seenivasagam S., Yiu P.H., Boonyuen S., Chung E.L.T., Lease J., Andou Y.

    Journal of Porous Materials   31 ( 5 )   1557 - 1575   2024年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    The reduction of nitrophenols is a broadly accepted model for catalytic processes. Incorporating nanostructures into porous materials is becoming more widely acknowledged for its great importance. This strategy has attracted much interest because of its exceptional features imparted on the catalysts, offering enormous promise in accelerating the reduction of nitrophenols. In recent years, various nanostructures have been embedded to a wide range of porous materials, such as carbon, silica, metal-organic frameworks, and other inorganic materials. These porous frameworks possess unique physical and chemical characteristics, making them well-suited for catalytic applications. This thorough review begins by explaining the mechanism of nitrophenol reduction, exploring several nanostructures based on noble metals that are commonly used for catalytic reduction. Following that, a systematic description and comparison of nitrophenols catalytic reduction using various nanostructures on porous templates such as carbon-based, silica-based, zeolite-based, polymer-based, and metal-organic frameworks (MOF) were explained. In addition, this paper also examines several functional materials to enhance the catalytic reduction of nitrophenols. Herein, this write-up intends to narrow the knowledge gap on the recently synthesized catalysts and the practical requirements for removing nitrophenol. This write-up is hoped to offer valuable insights that can aid in the practical utilization of these catalysts for wastewater remediation applications.

    DOI: 10.1007/s10934-024-01618-4

    Scopus

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  • Lignocellulosic biomass-derived carbon quantum dots (CQDs): A novel approach utilizing organosolv lignin from Moso bamboo waste 査読有り 国際誌

    Ahmad Farid M.A., Lease J., Yoshito A.

    Journal of Cleaner Production   467   2024年08月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    Converting lignocellulosic materials to carbon quantum dots (CQDs) has garnered significant interest to transform biomass wastes into highly valuable products. We chose to use lignin as our feedstock because high-value products more readily utilize cellulose and hemicellulose. Lignin, arguably the most underutilized and complex biopolymer within any biomass, presents an appealing yet overlooked opportunity. While some may argue that lignin-based CQDs are no longer groundbreaking, this is because existing studies typically rely on commercially available lignin, ignoring biomass-derived sources. Therefore, in our pioneering research, we utilized organosolv lignin, prized for its structural purity and extracted from Moso bamboo waste, as the carbon source in a facile two-step technique to synthesize luminous CQDs. The process involved the addition of 2,4-diaminobenzenesulfonic acid, a mild-organic acid that acted as a source for both nitrogen (N) and sulphur (S). A 12-h hydrothermal treatment at 200 °C with 0.1 M of acid addition attained the best result. The resultant CQDs display strong green fluorescence, with the highest quantum yield of 17.7% seen in N and S co-doped CQDs. With their obvious and specific fluorescence quenching impact on Fe<sup>3+</sup>, CQDs demonstrate great potential as a fluorescent nanoprobe for metal ion detection. This CQD nanoprobe responds very sensitively to Fe<sup>3+</sup> between 0 and 500 μM (R<sup>2</sup> = 0.9803), with a detection limit of 0.15 μM. This research not only presents a unique alternative nanoprobe for the sensing field using renewable biomass lignin, but it also paves the way for the long-term, cost-effective, and scalable manufacturing of CQDs.

    DOI: 10.1016/j.jclepro.2024.142852

    Scopus

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  • Catalytic efficiency and stability of biomass-derived sulfonated graphene catalysts in microwave-enhanced biodiesel production 査読有り 国際誌

    Ahmad Farid M.A., Mohd Johari S.A., Lease J., Ayoub M., Andou Y.

    Fuel   368   2024年07月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    The strategic integration of bio-based catalytic design principles and the intricacies of microwave irradiation offers a viable path to improving the sustainability and efficiency of biodiesel production. In this work, we produced novel biomass-derived sulfonated graphene oxide (bGO-SO<inf>3</inf>H) and reduced graphene oxide (brGO-SO<inf>3</inf>H), examining their collaborative effects with microwave irradiation on reaction efficacy. Sulfonation in catalysts was evident through 1) reduced mass loss during thermal decomposition (bGO-SO<inf>3</inf>H: 34.5 %; brGO-SO<inf>3</inf>H: 29.4 %) compared to precursors (bGO: 55.6 %; brGO: 20.3 %), indicating decreased oxygen-containing functional groups; 2) higher TPD-acidic sites (bGO-SO<inf>3</inf>H: 3.17 mmol g<sup>−1</sup>; brGO-SO<inf>3</inf>H: 3.24 mmol g<sup>−1</sup>), supported by titration-acid density (bGO-SO<inf>3</inf>H: 2.97 mmol g<sup>−1</sup>; brGO-SO<inf>3</inf>H: 3.83 mmol g<sup>−1</sup>); and 3) additional C<inf>1s</inf> peaks attributed to C-S bonds in sulfonic moieties and a significant increase in sp<sup>2</sup> carbon content compared to their precursors, confirmed by I<inf>D</inf>/I<inf>G</inf> ratio reduction (bGO-SO<inf>3</inf>H: 1.09 to 0.98, brGO-SO<inf>3</inf>H: 0.99 to 0.95). Despite modest surface areas (18–44 m<sup>2</sup>/g), both catalysts exhibited significantly elevated acid densities (0.05–4.83 mmol g<sup>−1</sup>) post-sulfonation. Under optimized conditions (2 wt% catalysts, 25:1 methanol-to-oil ratio, 25 min at 75 °C), bGO-SO<inf>3</inf>H yielded 90.97 % FAME yield, while brGO-SO<inf>3</inf>H achieved 97.45 % with a reduced dosage (1.5 wt%), shorter time (20 min), and less methanol (20:1). Despite catalytic deactivation, our study demonstrates reduced catalyst consumption, a lower reaction temperature, and a shortened conversion time compared to prior findings, thereby enhancing the efficiency of biodiesel production.

    DOI: 10.1016/j.fuel.2024.131580

    Scopus

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  • Kinetics and thermodynamics in microwave-assisted transesterification of palm oil utilizing sulphonated bio-graphene catalysts for biodiesel production 査読有り 国際誌

    Farid M.A.A., Mohd Johari S.A., Lease J., Ayoub M., Andou Y.

    Biomass and Bioenergy   185   2024年06月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    Enhanced reaction performance is what has piqued interest in using graphene-based catalysts in producing biodiesel. However, in-depth analyses were lacking from a kinetic and thermodynamic standpoint. This means that a well-designed experiment is necessary to determine the effect that the graphene catalysts have on the reaction rates and yields. This work addresses the kinetic and thermodynamic aspects of heterogeneously catalyzed transesterification using sulphonated biomass-derived graphene catalysts, i.e., bGO-SO<inf>3</inf>H and brGO-SO<inf>3</inf>H. It was accomplished using the pseudo-first order mechanism and the Eyring-Polanyi equation, with all data fitting satisfactorily in both models at the ideal reaction temperature of 353.15 K, resulting in R<sup>2</sup> values of 0.9784 (bGO-SO<inf>3</inf>H) and 0.9884 (brGO-SO<inf>3</inf>H). The calculated activation energy (Ea) was determined to be 44.45 and 51.73 kJ mol<sup>-</sup>1 for bGO- and brGO-SO<inf>3</inf>H, respectively. Additionally, the Gibbs free energy (ΔG) values were determined at −38.09 and −31.81 kJ mol<sup>−1</sup> for bGO- and brGO-SO<inf>3</inf>H, respectively. Meanwhile, the values for ΔH and ΔS were obtained as 41.69 kJ mol<sup>−1</sup> and 225.93 J mol<sup>−1</sup> K<sup>−1</sup>, respectively, and 48.96 kJ mol<sup>−1</sup> and 228.72 J mol<sup>−1</sup> K<sup>−1</sup>, respectively. These collective outcomes collectively signify the endothermic nature of the reaction and their spontaneity, particularly under elevated temperature conditions.

    DOI: 10.1016/j.biombioe.2024.107236

    Scopus

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  • Structural Metamorphosis of Graphitic Derivatives Produced from Fractionated Bamboo Lignin 査読有り 国際誌

    Ahmad Farid M.A., Lease J., Zheng A.L.T., Tsubota T., Andou Y.

    ACS Sustainable Resource Management   1 ( 1 )   97 - 113   2024年01月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    The demand for sustainable and renewable materials has prompted extensive research on lignocellulosic biomass as a potential feedstock for advanced nanomaterials. This article describes the sequential processes of iron-catalyzed graphitization, improved Hummer’s method, and low-temperature thermal annealing designed to transform ethanosolv lignin into bio-based graphene products. The lignin undergoes a metamorphosis during graphitization, transforming into turbostratic crystallite with a unique flake-like configuration at high temperatures in a tightly sealed muffle furnace. Following oxidation, the structure of the resultant graphite undergoes dynamic changes, leading to exfoliation-induced distancing of the sheets of graphene layers. Notwithstanding the reduction process, the geometrical morphology of its oxidized state remains unaltered, preserving the lamellar configuration. Notably, the resulting graphitized lignin showcases a substantial carbon content exceeding 75 wt % and a relatively low oxygen content below 16 wt %. In contrast, graphene oxides (GOs) exhibit elevated oxygen levels resulting from the introduction of oxygen moieties during the oxidation step, which subsequently diminishes following thermal annealing. Diffraction patterns confirm the presence of (001), (002), and (100) planes in all graphene-based materials, indicating an aromatic ring orientation. Oxidation affects interlayer spacing with GOs exhibiting larger distances than graphitized lignin and reduced graphene oxides (rGOs). Graphitization increases the sp<sup>2</sup>carbon composition by removing volatiles and mineral matter. Oxidation increases the sp<sup>3</sup>carbon composition, but it decreases after thermal annealing due to the partial removal of oxygen species, leading to a reorientation of the sp<sup>2</sup>carbon configuration.

    DOI: 10.1021/acssusresmgt.3c00048

    Scopus

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  • Effect of solvent and acid catalyst selection on lignin recovery and purity in autoclave-assisted organosolv extraction 査読有り 国際誌

    Farid M.A.A., Ibrahim I., Lease J., Tsubota T., Andou Y.

    Bioresource Technology Reports   24   2023年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)

    This study leverages the autoclave-assisted method to explore a range of acid catalysts (H<inf>2</inf>SO<inf>4</inf>, HCl, HNO<inf>3</inf>, H<inf>3</inf>PO<inf>4</inf>) and solvents (methanol, ethanol, acetone, 2-butanol, 2-propanol) for lignin extraction, with a focus on identifying optimal efficiency-enhancing combinations. By contrasting the performance of various acid catalysts and solvents, this work transcends previous efforts in this field. Notably, H<inf>2</inf>SO<inf>4</inf> yields the highest lignin recovery (44.7 %) but with lower purity (78.4 %) compared to HCl (85.7 %) in the same solvent. Methanol yields the highest recovery (45.1 %), yet lower purity (79.2 %) than ethanol (85.7 %) with a similar catalyst. A pivotal improvement lies in the elucidation of structural purity, substantiated by IR and NMR resulting signals, supported by microscale morphology and chemical composition (SEM-EDX). This study extends current understanding, providing profound insights into optimizing extraction procedures for producing lignin with desired attributes.

    DOI: 10.1016/j.biteb.2023.101622

    Scopus

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著書

  • Innovative Approaches of Landfill Gas Collection Systems in Landfill Sites for Efficient Methane Capture 査読有り

    Ahmad Farid M.A., Norrrahim M.N.F., Lease J., Andou Y.(共著)

    Handbook of the Effects of Landfill Emissions on Sustainable Development  2025年01月  ( ISBN:9783032019509, 9783032019516

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    記述言語:英語

    Methane emissions from landfills are a significant contributor to greenhouse gas emissions and climate change. This article, hence, presents strategies for landfill gas collection systems aimed at improving methane recovery. A comparative analysis of gas collection system designs, including horizontal, vertical, and slotted wells, is presented. Additionally, the utilization of vacuum-assisted gas collection systems and gas permeable barriers is discussed, highlighting the potential benefits and drawbacks of each approach. Challenges and opportunities in implementing innovative landfill gas collection systems are discussed, including technical, regulatory, and financial aspects. Collaboration between stakeholders is emphasized as crucial for the successful implementation and operation of these systems. The potential of innovative landfill gas collection systems for reducing greenhouse gas emissions from landfills is highlighted, and a call to action for further research and implementation of these approaches is made. This article provides valuable information for researchers, practitioners, and policymakers interested in sustainable waste management and climate change mitigation.

    DOI: 10.1007/978-3-032-01951-6_8

    Scopus

  • Air Pollution Control Strategies for Sustainable Landfill Management 査読有り

    Ahmad Farid M.A., Norrrahim M.N.F., Lease J., Andou Y.(共著)

    Handbook of the Effects of Landfill Emissions on Sustainable Development  2025年01月  ( ISBN:9783032019509, 9783032019516

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    記述言語:英語

    The integration of waste management and air pollution control strategies is essential for sustainable landfill management. Landfill sites are a significant source of air pollution, and current waste management practices and air pollution control technologies have limitations in reducing emissions. This article provides an overview of current practices and challenges in landfill management and discusses principles of sustainable landfill management. The article identifies key opportunities for integrating waste management and air pollution control strategies, including innovative approaches to landfill design and operation and advanced air pollution control technologies. The benefits of integrated strategies are discussed, including reduction of air pollution and associated health risks, energy recovery, and greenhouse gas emissions reduction, as well as economic and social benefits. Finally, the article presents challenges to the implementation of integrated strategies and identifies future research directions, emerging technologies, and trends. This article provides valuable information for researchers, policymakers, and decision-makers interested in sustainable waste management and air pollution control.

    DOI: 10.1007/978-3-032-01951-6_9

    Scopus

  • Biogas Production from Municipal Solid Waste (MSW) Insights into Feedstock Preparation and Upgrading Techniques 査読有り

    Farid M.A.A., Norrrahim M.N.F., Lease J., Andou Y.(共著)

    Generation of Energy from Municipal Solid Waste Circular Economy and Sustainability  2024年01月  ( ISBN:9783031743337, 9783031743344

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    記述言語:英語

    This chapter comprehensively explores biogas production from municipal solid waste (MSW), revealing its intricate process. Covering crucial aspects, it enhances our grasp of renewable energy extraction from waste. Examining feedstock preparation emphasizes its role in optimizing biogas production. Identifying suitableMSWtypes targets efficient waste utilization, redefining waste as a resource. The various stages involved in biogas production from MSW are outlined, and process optimization strategies to enhance biogas production are discussed in detail, including the influence of types ofwaste, feedstock preparation, and operating conditions on biogas yield. Strategies like co-digestion and innovative reactor design boost biogas production from MSW, enhancing efficiency. Technological advancements, including physiochemical and adsorption techniques, maximize biogas yield. Biogas applications in energy and heat underscore its positive impact. The article also highlights the opportunities and potential for biogas production from MSW, explaining its significance for the wider biogas industry.Yet, challenges, from finance to tech complexities, must be recognized for effective solutions. Acknowledging hurdles paves the way for realizing biogas potential. Considering opportunities and concerns offers a comprehensive view of MSW-based biogas production’s future. This analytical work is a valuable resource for advanced researchers, policymakers, and practitioners interested in sustainable waste management and renewable energy production.

    DOI: 10.1007/978-3-031-74334-4_14

    Scopus

  • Microplastic Reduction in Municipal Solid Waste (MSW) Landfill 査読有り

    Farid M.A.A., Norrrahim M.N.F., Lease J., Andou Y.(共著)

    Springer Water  2024年01月 

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    記述言語:英語

    Reduction of microplastics (MPs) release into the environment calls for a comprehensive strategy that employs scientific and technological innovation. The tracing of MPs from their origins in plastic waste streams to their discharge into multiple environmental compartments is an example of the complicated route that demands a thorough evaluation. It highlights diverse sources of MPs leachate, soil, and air that infiltrate ecosystems. By exploring abiotic and biotic degradation mechanisms, influenced by factors like plastic composition, landfill conditions, and waste age, this chapter reveals the intricate nature of MPs formation. Detection techniques for MPs degradation are discussed, providing a foundation for accurate assessment. The risks MPs pose in landfills-soil, -water, and -air contamination, impacting both health and ecosystems are highlighted. Ecotoxicological effects on terrestrial and aquatic life emphasize the urgency of addressing this issue. Existing approaches to MPs removal within MSW landfills are presented, from physical separation to enhanced biodegradation methods. These strategies offer potential solutions to mitigate MPs pollution.

    DOI: 10.1007/978-3-031-55665-4_3

    Scopus

口頭発表・ポスター発表等

  • Valorization of Bamboo Waste into Phosphorus-Functionalized Cellulose Nanofiber Film

    Jacqueline Lease, Yoshito Andou

    第13回高分子学会グリーンケミストリー研究会シンポジウム  第27回プラスチックリサイクル化学研究会研究討論会 合同発表会 

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    開催期間: 2026年08月06日 - 2026年08月07日   記述言語:英語  

  • Mechanochemical Synthesis of Esterified Biomass-derived Cellulose from Various Plant Sources for Bio-based Polymers

    Jacqueline Lease, Yoshito Andou

    IUPAC 51st World Polymer Congress (MACRO 2026) 

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    開催期間: 2026年07月28日 - 2026年07月31日   記述言語:英語  

  • Mechanochemical Functionalization of Bamboo-Derived Cellulose for Sustainable Biopolymers

    Jacqueline Lease, Yoshito Andou

    第1回ジャパン バンブー カンファレンス 

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    開催期間: 2026年06月26日   記述言語:英語  

  • Mechanochemical Esterification of Cellulose Toward Sustainable Plastics 招待有り

    Jacqueline Lease

    CWNU-Kyutech International Joint Research Symposium 

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    開催期間: 2026年03月03日   記述言語:英語  

  • Mechanochemical strategies for sustainable cellulose esters synthesis using vinyl esters

    Jacqueline Lease, Yoshito Andou

    The International Chemical Congress of Pacific Basin Societies 2025 

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    開催期間: 2025年12月15日 - 2025年12月20日   記述言語:英語  

  • Time-Efficient Transesterification of Celluolose via Mechanochemical Assisted Method

    Jacqueline Lease, Yoshito Andou

    Time-Efficient Transesterification of Celluolose via Mechanochemical Assisted Method 

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    開催期間: 2025年12月03日 - 2025年12月05日   記述言語:英語  

  • Efficient Fabrication of Cellulose-Derived Plastics Using Mixed Fatty Acid

    Jacqueline Lease, Yoshito Andou

    13th International Symposium on Applied Sciences and Engineering (SAES2025) 

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    開催期間: 2025年11月10日 - 2025年11月11日   記述言語:英語  

  • Synthesis of fluorescent cellulose derivatives toward smart and sustainable materials

    Jacqueline Lease, Yoshito Andou

    The 8th international Conference on Bio-based Polymers 2025 (ICBP 2025) 

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    開催期間: 2025年11月06日 - 2025年11月08日   記述言語:英語  

  • Mechanochemical Synthesis of Thermoplastic Cellulose Mixed Esters for Plastic Film ​

    Jacqueline Lease, Yoshito Andou

    第74回高分子討論会 

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    開催期間: 2025年09月16日 - 2025年09月18日   記述言語:英語  

  • A Streamlined Approach to Functionalized Cellulose-Based Plastic Films for Polymer Substitution​

    Jacqueline Lease, Yoshito Andou

    セルロース学会第32回年次大会 

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    開催期間: 2025年07月10日 - 2025年07月11日   記述言語:英語  

  • Sustainable Esterification Technique for Bio-Based Cellulose Esters Production​ 招待有り

    Jacqueline Lease, Yoshito Andou

    Asian Chemical Congress (ACC) 

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    開催期間: 2025年06月23日 - 2025年06月27日   記述言語:英語  

  • Optimizatin of Mechanical Properties of Cellulose Esters via Mechanochemica Esterification and Their Application Potential

    Jacqueline Lease, Yoshito Andou

    International Advanced Technology and Taiwan-Japan Engineering Forum, IAT&TJEF 2025 

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    開催期間: 2025年03月11日 - 2025年03月13日   記述言語:英語  

▼全件表示

工業所有権

  • 表面改質セルロースの製造方法

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    出願番号: 特願2021-132895  出願日:2021年08月17日

    公開番号:特開2023-027646  公開日:2023年03月02日

    登録番号:特許第7681895号 

学術関係受賞

  • Silver Award for Poster Presentation (IWCCR)

    International Workshop on Climate Change Resilience (IWCCR)   2025年12月05日

    Jacqueline Lease

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    受賞国:マレーシア