TSUGE Akihiko

写真a

Title

Professor

Laboratory

1-1 Sensui-cho, Tobata-ku, Kitakyushu-shi, Fukuoka

Research Fields, Keywords

Organic synthesis, Cyclophanes, Molecular recognition, Hydrogen bonding, Coordinarion molecule, Molecular assembly,Polymer

E-mail

E-mail address

Phone

+81-93-884-3317

Fax

+81-93-884-3075

Scopus Paper Info  
Total Paper Count: 0  Total Citation Count: 0  h-index: 6

Citation count denotes the number of citations in papers published for a particular year.

Undergraduate Education 【 display / non-display

  • 1980.03   Kyushu University   Faculty of Engineering   Graduated   JAPAN

Post Graduate Education 【 display / non-display

  • 1985.03  Kyushu University  Graduate School, Division of Engineering  Organic Synthesis  Doctoral Program  Accomplished Credits for Doctoral Program  JAPAN

Degree 【 display / non-display

  • Kyushu University -  Doctor of Engineering  1985.05

Biography in Kyutech 【 display / non-display

  • 2008.04
    -
    Now

    Kyushu Institute of TechnologyFaculty of Engineering   Department of Materials Science   Professor  

Academic Society Memberships 【 display / non-display

  • 2020.04
    -
    Now
     

    The Japanese Association for Organic Electron System  JAPAN

  • 2018.04
    -
    2019.03
     

    Chemical Society of Japan, Kyushu branch  JAPAN

  • 2017.10
    -
    2019.03
     

    The Japanese Association for Organic Electron System  JAPAN

  • 2017.04
    -
    2018.03
     

    Chemical Society of Japan, Kyushu branch  JAPAN

  • 2015.04
    -
    2017.03
     

    Chemical Society of Japan, Kyushu branch  JAPAN

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Research Career 【 display / non-display

  • Synthesis of cyclophane compounds and their characterization.

    Organic synthesis, Cyclophane, Molecular recognition, Dynamic structure  

    Project Year: 1994.04  -  Now 

  • Application of rotaxane compounds

    Organic synthesis, Catenane  

    Project Year: 2006.04  -  Now 

  • Development of novel gelation reagents

    gel  

    Project Year: 2009.04  -  Now 

Publications (Article) 【 display / non-display

  • Investigation of the hardener with latent and rapid curing based on phenol-amine salts for applications to cyanate ester resins.

    J. Ueyama, R. Ogawa, A. Tsuge, T. Endo

    J. Appl. Polym. Sci.  ( WIELY )    e5128   2021.06  [Refereed]

    DOI

  • Formation of Organogel In Situ Based on a Dynamic Imine Bond

    Tsuge A., Suehara, S., Takemori Y., Nakano, M., Araki K.

    Chem. Lett.    50 ( 5 ) 1091 - 1094   2021.05  [Refereed]

     View Summary

    A simple approach for creating organogel in situ through formation of a reversible imine bond known as a dynamic covalent bond is described. As the condensations of the glutamate-based amine compounds and salicylaldehyde or 2-hydroxy-1-naphthaldehyde in alcohols such as MeOH, EtOH and propanol as well as DMF proceed, gelation occurs in situ depending on the condition. Addition of a small amount of acid and water to a resultant gel induces its collapse due to returning to the corresponding amines and aldehydes. No such a gelation was observed when combining benzaldehyde or naphthaldehyde.

    DOI

  • Development of Organogelators and Ambidextrous Gelators Based on Molecular Design.

    Akihiko Tsuge

    Journal of Synthetic Organic Chemistry  ( Society of Synthetic Organic Chemistry )  79 ( 4 ) 300 - 310   2021.04  [Refereed]  [Invited]

    DOI

  • Development of novel aromatic ambidextrous gelators based on molecular design

    Tsuge A., Matsumoto S., Hashimura D., Araki K.

    Tetrahedron Letters    61 ( 7 )   2020.02  [Refereed]

     View Summary

    © 2019 Elsevier Ltd Although large amounts of organogelators and hydrogelators have been available, the ambidextrous gelators that can gelate both organic solvents, especially, apolar solvents and water are very limited. Furthermore, most of them have been found out incidentally. In order to create powerful ambidextrous gelators it should be necessary to tackle a bottom-up approach based on organic synthesis. Thus, according to molecular design the amphiphilic aromatic compounds consisting of glutamate- or aspartate-based structure having two long alkyl chains and some ethylene glycol units have been prepared. The glutamate-based amphiphilic compounds having one ethylene glycol unit or two ethylene glycol units exhibited an excellent ambidextrous capability because they can only gelate benzene, toluene and water, however, introduction of three ethylene glycol units prevented gelating water. On the other hand the corresponding aspartate-based amphiphilic compound showed no such ambidextrous properties.

    DOI Scopus

  • Gelating Abilities of Two-component System of Catecholic Derivatives and a Boronic Acid.

    Akihiko Tsuge, Ryota Kamoto, Daisuke Yakeya, Koji Araki

    Gels  ( MDPI )  5 ( 45 ) 5 - 14   2019.10  [Refereed]

    repository DOI

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Publications (Books) 【 display / non-display

  • ゲルの安定化と機能性付与・次世代への応用開発(共著)

    柘植顕彦 ( Single Work ,  錯体化を駆動力とした赤色発光型ゲル化剤の創製 )

    技術情報協会  2013.12

Conference Prsentations (Oral, Poster) 【 display / non-display

  • ウレタン構造を有する二官能性五員環カーボナートと多官能性アミンとの重付加によるネットワークポリヒドロキシウレタンの合成

    田中友也、吉田嘉明、荒木孝司、柘植顕彦、遠藤剛

    第70回ネットワークポリマー討論会  (関西大学)  2021.11  -  2021.11  合成樹脂工業協会

  • Synthesis of five-membered cyclic carbonates and their cation ring-opening polymerization behavior.

     [Invited]

    (Online)  2021.07  -  2021.07 

  • Synthesis and characterization of gelators consisting of 1,2,3-triazole unit.

     [Invited]

    (Online)  2021.07  -  2021.07 

  • Preparation and properties of low molecular weight gelators that have both hydrophilicity and hydrophobicity.

     [Invited]

    (Online)  2021.07  -  2021.07 

  • Coupling control of G-quadruplex (G4) ligands by light.

     [Invited]

    (Online)  2021.07  -  2021.07 

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Lectures 【 display / non-display

  • Organogelators Derived from the [3.3]Metacyclophane Skeleton and the Europium Complex

    The 7th Taiwan-Japan Bilateral Symposium on Architecture of Functional Organic Molecules   2012.10.23 

  • Aspects of Small-sized Cyclophanes in Terms of Weak Interactions

      2012.10.15 

 

Activities of Academic societies and Committees 【 display / non-display

  • 2020.04
    -
    Now

    The Japanese Association for Organic Electron System  

  • 2017.10
    -
    2020.03

    The Japanese Association for Organic Electron System  

  • 2017.04
    -
    2018.03

    The Chemical Society of Japan  

  • 2016.04
    -
    2017.03

    The Chemical Society of Japan  

  • 2015.04
    -
    2016.03

    The Chemical Society of Japan  

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