研究者詳細 - 森口　哲次

論文 - 森口　哲次

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Ultrasound-assisted removal of contaminants on stainless steel surfaces using nitrogen ultrafine bubble water 査読有り国際誌

Nakahara M., Watanabe S., Kimura S., Sasaki M., Inagaki H., Moriguchi T.

Progress in Nuclear Energy 172 2024年07月

担当区分：最終著者記述言語：英語掲載種別：研究論文（学術雑誌）

In this study, a novel ultrasound-assisted removal/decontamination process using ultrafine bubbles (UFBs) of 1 μm or less diameter gas bubbles is proposed to reduce secondary radioactive waste for decommissioning of nuclear installations. The removal/decontamination technique does not require abrasive media for abrasive-blasting decontamination or chemical reagents for chemical decontamination. The removal experiments with simulated contaminants (Co oxides) on the surface of a stainless steel 316 (SUS316) plate were conducted, and the removal performance was confirmed using UFB water via ultrasonic irradiation at 1.6 MHz. The experimental results indicate that the UFBs adhere to the contaminants and move into the cracked Co oxides and the gap between the contaminants and the SUS316 plate. The vibration of UFBs and the impact due to the collapse of cavitation bubbles emitting ultrasound will exfoliate the contaminants. Decontamination experiments using fuel pin end plugs contaminated with radioactive materials, such as 60Co, were performed to evaluate the decontamination performance of various kinds of contaminants. The decontamination performance of 60Co in the fuel pin end plugs was different from that of non-radioactive Co oxides in the removal experiments, and the difference in the chemical states of Co affects the removal/decontamination behavior in the N2-UFB water. Therefore, understanding the properties of contaminants before the decontamination operation is necessary to maximize the decontamination performance with UFBs.

DOI： 10.1016/j.pnucene.2024.105195

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STRAD project for systematic treatments of radioactive liquid wastes generated in nuclear facilities 査読有り国際誌

Watanabe S., Ogi H., Arai Y., Aihara H., Takahatake Y., Shibata A., Nomura K., Kamiya Y., Asanuma N., Matsuura H., Kubota T., Seko N., Arai T., Moriguchi T.

Progress in Nuclear Energy 117 2019年11月

記述言語：英語掲載種別：研究論文（学術雑誌）

A new collaborative research project for systematic treatments of radioactive liquid wastes containing various reagents generating in nuclear facilities was started from 2018 initiated by Japan Atomic Energy Agency. The project was named as STRAD (Systematic Treatments of RAdioactive liquid wastes for Decommissioning) project. Tentative targets to be studied under the project are aqueous and organic liquid wastes which have been generated by experiments and analyses in a reprocessing experimental laboratory of JAEA. Currently fundamental studies for treatments of the liquid wastes with complicated compositions are underway. In the STRAD project, process flow for treatment of ammonium ion involved in aqueous waste was designed though the inactive experiments, and decomposition of ammonium ion using catalysis will be carried out soon. Adsorbents for recovery of U and Pu from spent solvent were also developed. Demonstration experiments on genuine spent solvent is under planning.

DOI： 10.1016/j.pnucene.2019.103090

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Investigation into the molecular and electronic structures of a newly synthesized o-quinone derivative 査読有り国際誌

Hamamoto N., Arae S., Moriguchi T., Irie R., Fujimoto H.

Chemical Physics 524 77 - 84 2019年08月

記述言語：英語掲載種別：研究論文（学術雑誌）

We studied on the geometric and electronic structures of a newly synthesized compound, 3-(tert-butyl)dinaphtho[1,2-b;1′,2′-d]furan-12,13-dione (1), having a twisted molecular structure at an o-quinone region in a crystal. The density functional theory (DFT)has been applied to investigate the geometric and electronic structures using the model compound (1H), where a tertiary butyl group of the compound 1 is replaced by a hydrogen atom. The optimized geometry for the model dimer of 1H represented well the twisted molecular structure of 1. The time-dependent DFT method explained the observed optical properties of 1 in a solution and a powdery solid. The DFT calculations also gave a good estimation of the ionization potential and the electron affinity of 1H, explaining a similarity in reduction and a difference in oxidation between 1H and o-benzoquinone. This similarity in the electron affinity was confirmed by measuring a reduction potential of the compound 1 with cyclic voltammetry.

DOI： 10.1016/j.chemphys.2019.04.033

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Design, Synthesis, Crystal Structure and Photophysical Properties of New Oxadiazole Extended Viologen Fluorophore 査読有り国際誌

Tetsuji Moriguchi, Masataka Okuyama, Venkataprasad Jalli

Crystal Structure Theory and Applications ( Scientific Research Publishing Inc. ) 2021 ( 10 ) 27 - 37 2021年03月

Design, Synthesis, Crystal Structure and Photoluminescence Properties of Four New Europium (III) Complexes with Fluorinated β-Diketone Ligand 査読有り国際誌

Tetsuji Moriguchi, Hiromasa Kawata, Venkataprasad Jalli

Crystal Structure Theory and Applications ( Scientific Research Publishing Inc. ) 2021 ( 10 ) 1 - 13 2021年02月

Synthesis, characterization and photophysical properties of two novel n-type semiconductor materials with trifluoromethyl and cyano groups 査読有り国際誌

Tetsuji Moriguchi, Daisuke Yakeya, Venkataprasad Jalli

Journal of Molecular Structure ( Elsevier ) 2019 ( 1185 ) 403 - 409 2019年05月

Synthesis of three new thiophene condensed pyrene derivatives, crystal structure and evaluation of their photophysical properties 査読有り

Moriguchi T., Yakeya D., Tsuge A., Jalli V.

Journal of Molecular Structure 1157 348 - 354 2018年04月

記述言語：英語掲載種別：研究論文（学術雑誌）

© 2017 Elsevier B.V. Three new thiophene condensed fluorescent pyrene derivatives have been synthesized by a two-step process, via. Wittig reaction followed by iodine promoted photocyclization. These molecules have been characterized by1H NMR and EI-MS. Further, the molecular structures of 4a, 4b and 4c has been confirmed by single crystal X-ray diffraction analysis. The protons located in the fjord and cove-regions of molecules 4b and 4c showed downfield shifts of the protons. Molecule 4a crystallized under monoclinic system with space group P21/c, molecule 4b crystallized under monoclinic system with space group C2/c and the molecule 4c crystalized under triclinic system with space group P-1. Molecules 4a, 4b and 4c showed strong absorption maxima wavelengths at 305, 358 and 330 nm, respectively. The molar extinctinction coefficients (ε) of the compounds 4a, 4b and 4c indicated molecule 4c has better ability to absorb UV light, molecule 4b has better fluorescence intensity than molecule 4a and 4c.

DOI： 10.1016/j.molstruc.2017.12.081

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On-off switching of gel formation by red-ox reaction 査読有り

Yakeya D., Moriguchi T., Tsuge A.

Tetrahedron Letters 59 ( 8 ) 712 - 714 2018年02月

記述言語：英語掲載種別：研究論文（学術雑誌）

© 2018 Elsevier Ltd Organogelator candidates which consist of the ferrocene unit have been prepared. It has been suggested that two amino acid residues in the structure are necessary to form a stable organogel. Addition of an oxidizing agent such as NaClO induces the collapse of the gel, and reproduction of the gel was observed by addition of a reducing agent such as glutathione. It has been found out that the on-off switching of gel formation can be achieved by red-ox reaction.

DOI： 10.1016/j.tetlet.2018.01.013

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Synthesis, crystal structure and photo physical properties of isomeric fluorinated s-shaped polyaromatic dibenzo[c,l]chrysene derivatives 査読有り

Moriguchi T., Tabuchi D., Yakeya D., Tsuge A., Jalli V., Yoza K.

Journal of Molecular Structure 1152 37 - 43 2018年01月

記述言語：英語掲載種別：研究論文（学術雑誌）

© 2017 Elsevier B.V. Two s-shaped fluorinated isomeric polyaromatic dibenzo[c,l]chrysene derivatives have been synthesized by a two step process using the Wittig, Heck and iodine promoted cyclization reactions. These cyclized compounds were characterized by1H NMR and EI-MS. Further, absolute configurations of isomeric 4a and 4b were determined by X-ray diffraction analysis. Compound 4a crystallized under monoclinic system with space group P21/c and compound 4b crystallized under monoclinic system with space group Cc. They have good solubility in common organic solvents such as dichloromethane, chloroform and THF. Photophysical properties of 4a and 4b were evaluated by using UV–Visible and Fluorescence spectrophotometer. Compounds 4a and 4b showed strong absorption maximum wavelength at 317 nm. The emission spectra of 4a and 4b displayed sharp peaks in the visible region from 417 to 441 nm. The shape of the UV–Visible and Fluorescence spectra of 4a and 4b looks almost identical. But compound 4a exhibited better fluorescence intensity than compound 4b. This difference may be due to the difference in the configuration of compounds 4a and 4b.

DOI： 10.1016/j.molstruc.2017.09.057

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Synthesis of two novels-shaped dibenzo[c,l] chrysene derivatives, crystal structure, and the evaluation of their photophysical properties 査読有り

Moriguchi T., Tabuchi D., Yakeya D., Tsuge A., Jalli V.

Crystals 7 ( 8 ) 2017年08月

記述言語：英語掲載種別：研究論文（学術雑誌）

© 2017 by the authors. Licensee MDPI, Basel, Switzerland. Two s-shaped polyaromatic dibenzo[c,l]chrysene derivatives have been synthesized by a two-step process, via. The Wittig reaction, followed by iodine, promoted photocyclization. These molecules have been characterized by 1 H NMR, FAB-MS, and elemental analysis. Further, the molecular structures of 4a and 4b have been confirmed by single crystal X-ray diffraction analysis. The protons located in the cove-regions of molecules 4a and 4b showed downfield shifts of the protons. Molecule 4a crystallized under the monoclinic system with space group C2/c, and the molecule 4b crystallized under the monoclinic system with space group P2 1 /n. Molecules 4a and 4b showed strong absorption maxima wavelengths at 310 nm and 324 nm, respectively. The molar extinctinction coefficients (ε) of the compounds 4a and 4b indicated that molecule 4b has a better ability to absorb UV light than molecule 4a. The emission spectra of the molecules 4a and 4b displayed peaks in the region 429–456 nm. The shape of the UV-Visible and Fluorescence spectra of the molecules 4a and 4b look almost identical. However, molecule 4b exhibited better fluorescence intensity than molecule 4a. This may be due to the difference in the substituents of molecules 4a and 4b.

DOI： 10.3390/cryst7080251

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Design and properties of glutamic acid-based coumarin derivatives as organogelators 査読有り

Yakeya D., Kitou N., Kinugawa S., Moriguchi T., Tsuge A.

Tetrahedron 73 ( 27-28 ) 3973 - 3978 2017年07月

記述言語：英語掲載種別：研究論文（学術雑誌）

© 2017 Two kinds of glutamaic acid-based coumarin derivatives show a quite different trend against gelation in organic solvents in terms of inter- or intramolecular hydrogen bonds involved. It has been found out that addition of the valinate structure into the coumarine derivative could improve its gelation ability.

DOI： 10.1016/j.tet.2017.05.074

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The syntheses, crystal structure and luminescence properties of cone-like octadentate europium (III) complexes with four short alkoxy substituents 査読有り

Moriguchi T., Hirosaki S., Jalli V., Tsuge A., Yoza K.

Crystals 7 ( 3 ) 2017年03月

記述言語：英語掲載種別：研究論文（学術雑誌）

© 2017 by the authors. Licensee MDPI, Basel, Switzerland. Treatment of 1-(4′-methoxy or ethoxy phenyl)-4,4,4-trifluoro-1,3-butanedione with europium (III) chloride in the presence of piperidine resulted in the halide ligands exchange yielded new piperidinium tetrakis{1-(4′-methoxy or ethoxy phenyl)-4,4,4-trifluoro-1,3-butanedionato} europate (III) complexes 2a and 2b. Complexes 2a and 2b have been characterized by elemental analysis, 1 H NMR spectroscopy, and FAB-MS, and their absolute structures were determined by single crystal X-ray diffraction analysis. The complexes 2a and 2b have the monoclinic space groups C2/c (No. 15, 4′-substituent = OCH 3 ) and with P − 1 (No. 2, 4′-substituent = OC 2 H 5 ), respectively. X-ray analysis results showed that eight coordinate structures of the complexes 2a and 2b have conelike structures, like calix[4]arenes, but their structures were slightly different due to the crystal packing and the existence of the solvent molecule. The complexes 2a and 2b exhibited identical, strong photoluminescence emissions in the solution phase.

DOI： 10.3390/cryst7030085

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Synthesis, characterization and air stable semiconductor properties of thiophene-condensed pyrene derivatives 査読有り

Moriguchi T., Higashi M., Yakeya D., Jalli V., Tsuge A., Okauchi T., Nagamatsu S., Takashima W.

Journal of Molecular Structure 1127 413 - 418 2017年01月

記述言語：英語掲載種別：研究論文（学術雑誌）

© 2016 Elsevier B.V. New and simple polyaromatic compounds containing two thiophene rings were prepared via photo-cyclization and their structural and photophysical properties were evaluated via 1 H NMR spectroscopy and X-ray crystallographic analysis. On the basis of X-ray analysis, it was determined that the molecular structure of the compound was highly strained and that they contain two hetero [4] helicene moieties. The compounds were investigated as active layer in p-type organic field-effect transistors (p-OFET) in top contact type devices. Notably, the compound containing two thiophene components exhibited very stable p-type semiconducting behavior in moist air.

DOI： 10.1016/j.molstruc.2016.07.104

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2,5-Bis(3,4-dimethoxyphenyl)-1,3,4-oxadiazole 査読有り

Tetsuji Moriguchi, Ryota Kamoto, Venkataprasad Jalli, Akihiko Tsuge

IUCr DATA 1 x160167 - x160167 2016年02月

One-pot four component synthesis of novel 3-furyl coumarin derivatives 査読有り

VENKATA PRASAD JALLI, SUVRATHA KRISHNAMURTHY, TETSUJI MORIGUCHI,AKIHIKO TSUGE

Journal of Chemical Sciences 128 ( 2 ) 217 - 226 2016年02月

Efficient synthesis of novel pyrrolo[2,3-c]pyridone derivatives using the Ugi four-component reaction followed by condensation reaction 査読有り

VenkataPrasad J., Krishnamurthy S., Moriguchi T., Tsuge A.

New Journal of Chemistry 41 ( 1 ) 97 - 107 2016年01月

記述言語：英語掲載種別：研究論文（学術雑誌）

© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. An efficient, mild and multicomponent synthesis of novel heterocyclic compounds possessing the pyrrolo[2,3-c]pyridone backbone was achieved using the Ugi four-component reaction and post-condensation of the Ugi adduct. This method offers many advantages, such as an easy handling procedure, atom economy, short reaction time, and a huge molecular library that can be synthesized by changing the substituents on the four independent starting materials. This methodology was also successfully employed for the electron deficient anilines and phenyl glyoxylic acids having CF 3 group. All the products were characterized using NMR ( 1 H and 13 C) spectroscopy and FAB mass spectrometry. Product 6g was further characterized by X-ray diffraction analysis.

DOI： 10.1039/C6NJ02569B

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syn-6,15-Dihydroxy-2,11-dithia[3.3]metacyclophane ethyl acetate monosolvate 査読有り

Tetsuji Moriguchi, Daisuke Miyamoto, Ventakaprasad Jalli, Kenji Yoza, Akihiko Tsuge

IUCr DATA 1 x160082 - x160082 2016年01月

3,5,7-Triacetoxy-2-(3,4-diacetoxyphenyl)-4H-1-benzopyran-4-one 査読有り

Tetsuji Moriguchi, Kozue Sakao, De-Xing Hou, Kenji Yoza

IUCr DATA 1 x160028 - x160028 2016年01月

Organogelators based on metacyclophane skeleton having urea units in the bridge 査読有り

Tsuge A., Fujiwara T., Yakeya D., Kawasaki H., Moriguchi T., Araki K.

Tetrahedron 71 ( 50 ) 9429 - 9432 2015年12月

記述言語：英語掲載種別：研究論文（学術雑誌）

© 2015 Elsevier Ltd.All rights reserved. Metacyclophanes having the urea units in their bridge have been prepared. It has been found out that some of them afford stable organogels in some solvents. It was also observed that addition of fluoride anion broke DMSO gel, and then this gel was formed again by addition of MeOH.

DOI： 10.1016/j.tet.2015.10.056

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Crystal structure of ethyl 2-(2-{1-[N-(4-bromophenyl)-2-oxo-2-phenylacetamido]-2-tert -butylamino-2-oxoethyl}-1H-pyrrol-1-yl)acetate 査読有り

Tetsuji Moriguchi, Venkataprasad Jalli, Suvratha Krishnamurthy, AkihikoTsuge, Kenji Yoza

Acta Crystallographica Section E E71 o1049 - o1050 2015年12月

Crystal structure of 3,4-dimethyl 2-(tert -butylamino)-5-[2-oxo-4-(thiomorpholin-4-yl)-2Hchromen-3-yl]furan-3,4-dicarboxylate ethyl acetate hemisolvate 査読有り

Tetsuji Moriguchi, Venkataprasad Jalli, Suvratha Krishnamurthy, AkihikoTsuge and Kenji Yoza

Acta Crystallographica Section E E71 o1003 - o1004 2015年12月

SYNTHESIS OF NOVEL SPIRO[INDOL-2,20-PYRROLES] 査読有り

Venkataprasad Jalli, Suvratha Krishnamurthy, Hiroyoshi Kawasaki, Tetsuji Moriguchi, and Akihiko Tsuge

Synthetic Communications 45 2216 - 2226 2015年09月

Crystal structure of (1R,4R)-tert-butyl 3-oxo-2-oxa-5-azabicyclo[2.2.2]octane-5-carboxylate 査読有り

Krishnamurthy S., Jalli V., Vagvala T., Moriguchi T., Tsuge A.

Acta Crystallographica Section E: Crystallographic Communications 71 ( 7 ) o449 - o450 2015年07月

記述言語：英語掲載種別：研究論文（学術雑誌）

In the title compound, C 11 H 17 NO 4 , commonly known as Ntert-butoxycarbonyl-5-hydroxy-D-pipecolic acid lactone, the absolute configuration is (1R,4R) due to the enantiomeric purity of the starting material which remains unchanged during the course of the reaction. In the crystal there no intermolecular hydrogen bonds.

DOI： 10.1107/S2056989015010476

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Crystal structure of benzyl 3-oxo-2-oxa- 5-azabicyclo[2.2.1]heptane-5-carboxylate 査読有り

Krishnamurthy S., Jalli V., Vagvala T., Moriguchi T., Tsuge A.

Acta Crystallographica Section E: Crystallographic Communications 71 ( 7 ) o447 - o448 2015年07月

記述言語：英語掲載種別：研究論文（学術雑誌）

The title compound, C1 3 H 13 NO 4 (also known as N-benzyloxycarbonyl- 4-hydroxy-l-proline lactone), crystallizes with two molecules in the asymmetric unit. They have slightly different conformations: the fused ring systems almost overlap, but different C-O-C-C torsion angles for the central chains of -155.5 (2) and -178.6 (2)° lead to different twists for the terminal benzene ring. In the crystal, the molecules are linked by C-H⋯O interactions, generating a three-dimensional network. The absolute structure was established based on an unchanging chiral centre in the synthesis.

DOI： 10.1107/S2056989015010464

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Preparation and structural properties of highly twisted polycyclic aromatic 査読有り

Tetsuji Moriguchi, Naoya Kitou, Takuya Iwamoto, Kenji Yoza and Akihiko Tsuge

Journal of Chemical Research 39 351 - 356 2015年06月

α-Chymotrypsin and l-acylase aided synthesis of 5-hydroxypipecolic acid via Jacobsen's hydrolytic kinetic resolution of epoxy amino acids 査読有り

Krishnamurthy S., Venkataprasad J., Chand Vagvala T., Moriguchi T., Tsuge A.

RSC Advances 5 ( 64 ) 52154 - 52160 2015年01月

記述言語：英語掲載種別：研究論文（学術雑誌）

© The Royal Society of Chemistry. Diethyl malonate derivatives were used to synthesize racemic 2-amino-5-hexenoic acid. These racemic 2-amino-5-hexenoic acid (homoallylyglycine) derivatives were efficiently resolved aided by α-chymotrypsin or l-acylase, giving rise to l- and d-enantiomers. These isolated enantiomerically pure amino acids with tert-butoxycarbonyl (Boc) protection were oxidised with 3-chloroperbenzoic acid. The oxidation gave rise to inseparable diastereomeric epoxides due to a newly generated chiral center at the C 5 carbon. The isolation of one of the diastereomeric epoxides was possible by selectively converting the remaining diastereomer into a dihydroxyl compound catalysed by Jacobsen's hydrolytic kinetic resolution (HKR). The isolated epoxide was regioselectively attacked by LiBr to give vicinal halohydrin, with bromide attacking the terminal C 6 carbon. Boc deprotection of the halohydrin led to intramolecular cyclization by attack of free amine at the C 6 carbon, generating a single isomer of 5-hydroxypipecolic acid which was effortlessly recovered in good yield after re-protection of the amine with the Boc group. Similarly the dihydroxyl compound isolated earlier was converted to a halohydrin with iodine at the C 6 carbon. This was feasible by efficient regioselective mono-tosylation with catalytic Bu < inf > 2 < /inf > SnO followed by iodine substitution. This was utilized to synthesize the 5-hydroxypipecolic acid derivative in the same described sequence consisting of Boc removal by acid treatment, cyclization, reprotection and purification. Finally the same sequence was repeated with the d-isomer and two diastereomers were isolated.

DOI： 10.1039/c5ra09207h

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Long-term air-stable n-channel organic thin-film transistors using 2,5-difluoro-1,4-phenylene-bis{2-[4-(trifluoromethyl)phenyl]acrylonitrile} 査読有り

Nagamatsu S., Oku S., Kuramoto K., Moriguchi T., Takashima W., Okauchi T., Hayase S.

ACS Applied Materials and Interfaces 6 ( 6 ) 3847 - 3852 2014年03月

記述言語：英語掲載種別：研究論文（学術雑誌）

A long-term air-stable n-type organic semiconductor, 2,5-difluoro-1,4- phenylene-bis{2-[4-(trifluoromethyl)phenyl]acrylonitrile}, was synthesized by a high-yield simple procedure of Knoevenagel condensation with aldehyde and acetonitrile derivatives. A fabricated organic thin-film transistor (OTFT) using this compound exhibited good n-channel OTFT properties with a high electron mobility of 0.17 cm 2 V -1 s -1 and an on/off current ratio of 10 6 under both vacuum and ambient air operation. After storage in ambient air for 1 year, a stored n-channel OTFT still shows good n-channel OTFT performance with little degradation in ambient air operation. © 2014 American Chemical Society.

DOI： 10.1021/am404549e

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Regulation of dynamic structure of cyclophanes by their complexation with the porphyrin 査読有り

Akihiko Tsuge,Masahiro yokoo,Hiroyoshi Kawasaki,Daisaku Kaneko,Tetsuji Moriguchi,Koji Araki

Tetrahedron Letters 54 6181 - 6184 2013年11月

Formation of Luminescent Organogels from the Europium-based Complexes 査読有り

Akihiko Tsuge, Daisuke Yakeya,Daisaku Kaneko,Tetsuji Moriguchi,Kouji Araki

Chemistry Letters 42 ( 3 ) 263 - 265 2013年03月

Photoemission study on double-decker type bis(phthalocyaninato)tin(IV) and its complexes 査読有り

Honda T., Ohya Y., Sumimoto M., Moriguchi T., Hori K., Fujimoto H.

Chemical Physics 407 110 - 114 2012年10月

記述言語：英語掲載種別：研究論文（学術雑誌）

Ultraviolet photoelectron spectroscopy (UPS) has been applied to investigate the valence electronic structures of the double-decker type phthalocyanine compound, bis(phthalocyaninato)tin(IV) (SnPc 2 ). The binding energies of spectral features were precisely determined and compared to those of tin(II) and lanthanide compounds. Two peaks were observed at 5.1 1 and 6.0 4 eV in the lower binding energy region, which corresponded to the molecular orbitals generated by the anti-bonding and bonding interactions between the orbitals of the two phthalocyanine rings, respectively. It is worthy to note that the ionization threshold of SnPc 2 is remarkably small as compared to other phthalocyanine compounds, implying ease of oxidation. Actually, oxidized forms of SnPc 2 were easily obtained by both chemical and electrochemical reactions, and their electronic structures were discussed in comparison with that of SnPc 2 and with the recent results of the density functional theory calculations. © 2012 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.chemphys.2012.09.015

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Conformational Regulation of Cyclophanes by Formation of Pseudorotaxane Based on a Charage-transfer Complex 査読有り

Akihiko Tsuge,Katsuji Nakamura,Tetsuji Moriguchi,Kouji Araki

Chemistry Letters 41 ( 9 ) 880 - 882 2012年09月

Preparation of syn and anti cyclophanes having oligothiophene units and their spectral properties. 査読有り

Akihiko Tsuge,Takeshi Hara,Tetsuji Moriguchi

Tetrahedron Letters 50 4509 - 4511 2009年04月

Preparation,Structure, and Spectral Properties of Cyclophane Consisting of Oligothiphene Units 査読有り

Akihiko Tsuge,Takeshi Hara,Tetsuji Moriguchi,Minoru Yamaji

Chemistry Letters 37 ( 8 ) 870 - 871 2008年04月

Structure and Conformational Properties of Three-layered Cyclophanes prepared by One-pot Synthesis 査読有り

Akihiko Tsuge,Takahiro Okamoto,Tetsuji Moriguchi

Ｊ．Ｃｈｅｍ．Ｒｅｓ． 2007 ( 7 ) 429 - 431 2007年04月

Spectral Properties and Charge-Transfer Complexes of the Cyclophanes Having the pyrene Moiety 査読有り

Akihiko Tsuge,Yukihiro Ikeura,Tetsuji Moriguchi,Minoru Yamaji

Chemistry Letters 36 ( 8 ) 1016 - 1017 2007年04月

Photochemical and Host-Guest Properties of Novel Europium Complexes 査読有り

森口哲次,和田佳子,豊瀬泰司,柘植顕彦

Proceedings of 16th International Conference on Photochemical Conversion and Storage of Solar Energy 2006年07月

Self Assembled Coordination Cage Derived from Small-Sized Pyridinophanes 査読有り

Akihiko Tsuge,Ayumi Matsubara,Tetsuji Moriguchi,Yoshihisa Sei,Kentaro Yamaguchi

Tetrahedron Letters 47 6607 - 6609 2006年04月

Synthese,Structural Properties, and Charge Transfer Complexesof Pyrenophanes 査読有り

Akihiko Tsuge,Waka Megumi Otsuka,Tetsuji Moriguchi,Kazunori Sakata

Org. Biomol. Chem. 19 3590 - 3593 2005年10月

Preparation and Photochemical Properties of Novel Europium Complexes 査読有り

森口哲次,柘植顕彦,早瀬修二

Proceedings of 15th International Conference on Photochemical Conversion and Storage of Solar Energy 2004年07月

Preparation and Molecular Arrangement of Novel Anthracenophanes 査読有り

Akihiko Tsuge,Waka Iwasaki,Tetsuji Moriguchi,Kazunori Sakata

Chem.Lett. 2004 756 - 757 2004年05月

Preparation and Stractural Properties of Thiametacyclophanes having Pyridine Rings 査読有り

Tetsuji Moriguchi,Kanako Kamada,Akihiko Tsuge,Kazunori Sakata

J.Chem.Res. 2004 165 - 169 2004年03月

Preparation and Structural Properties of Novel Fluorenophanes 査読有り

Akihiko Tsuge,Hideaki Nishimoto,Tetsuji Moriguchi,Kazunori Skata

Chem.Lett. 2003 776 - 777 2003年08月

Preparationb and Photochemical Properties of Novel Lanthanide(III) Complexes 査読有り

森口哲次,鷹野秀樹,柘植顕彦

Proceedings of 2002 IAMS International Symposium on Preparation of New Materials for LC and EL Display on Institute of Advanced Material Study, Kyushu University, Kasuga(2002) 71 - 74 2002年09月

Preparation and Molecular Arrangement of Novel　Pyrenophanes 査読有り

Akihiko Tsuge,Yuuji Tanba,Tetsuji Moriguchi,Kazunori Skata

Chem.Lett. 2002 384 - 385 2002年03月

Intra- and Intermolecular Interactions in Dithiametacyclophane Systems 査読有り

柘植顕彦,森口哲次

Proceeding of The 10th International Symposium on Novel Aromatics 2001年07月

Inter-and Intramolecular Interaction in Substituteddithia[3. 3]metacyclophanes. 査読有り

未入力

J. Chem. Soc., Perkin Trans. 2 ( 6 ) 934 - 938 2001年04月

Syntheses and structures of dichloropalladium(II)(dithia[3. 3]dipyridinophane)and dichloroplatinum(II)(dithia[3. 3]dipyridinophane)complexes. 査読有り

未入力

Polyhedron 20 ( 18 ) 2315 - 2320 2001年04月

Conformational Properties and Intramolecular Weak Interactions in Substituted Dithia[3. 3]metacyclophanes 査読有り

未入力

Chem. Lett. 586 - 587 2001年04月

Synthesis and electrochemical properties of bis([2. 2]metacyclop0hane)bipyridinium 査読有り

未入力

J. Chem. Res.(S) 250 - 252 2001年04月

Preparation, conformation, and reactivities of metacyclophanes consisting of three aromatic rings 査読有り

井上恵,森口哲次,柘植顕彦

Proceeding of International Chemical Congress of Pacific Basin Socieries 458 - 458 2000年12月

Syntheses, spectroscopic properties and X-ray crystal structures of tris(tfacametacyclophane)(bpy)europium(III)and piperidinium tetrakis(ptolutfacac)europate(III)complexes. 査読有り

未入力

Polyhedron 19 ( 7 ) 785 - 790 2000年04月

Preparation and Characterization of Five-Coordinate Zinc(II)Complexes of H2tmtaa, (An(tmtaa)L[L=PPh3, OPPh3 and CH3CN])and Crystal Structure of Zn(tmtaa)OPPh3. 査読有り

未入力

Synth. React. Inorg. Met.-Org. Chem. 30 ( 1 ) 73 - 87 2000年04月

Preparation, Conformation and Reaction of Medium-sized[1. n. n]Metacyclophanes. 査読有り

未入力

Chem. Lett. 948 - 949 2000年04月

Synthesis and Properties of Metacyclophanes Consisting of Three Aromatic Rings 査読有り

井上恵,森口哲次,柘植顕彦

Proceedings of 1999 IAMS International Seminar on New Reactions and Novel Structures on Institute of Advanced Material Study 145 - 146 1999年12月

Synthesis and Conformational Properties of 1,8-Bridged fluorenophanes 査読有り

灘良輔,森口哲次,柘植顕彦

Proceedings of 1999 IAMS International Seminar on New Reactions and Novel Structures on Institute of Advanced Material Study 137 - 142 1999年12月

Preparation and Characterization of Dithia[3.3]meta-cyclophanes 査読有り

森口哲次,柘植顕彦

Proceedings of 1999 IAMS International Seminar on New Reactions and Novel Structures on Institute of Advanced Material Study 39 - 42 1999年12月

Preparation and Conformational Properties of Novel Fluorenophanes 査読有り

柘植顕彦,森口哲次,灘良輔,野口雄二

Proceedings of 9th International Symposium on Tohwa University 203 - 206 1999年11月

Inter- and Intramolecular Weak Inbteraction in Dithia[3.3]meta-cyclophanes 査読有り

森口哲次,柘植顕彦

Proceedings of 9th International Symposium on Tohwa University 99 - 102 1999年11月

Conformational and Intramolecular Hydrogen-Bonding Properties of Substituted Dithia[3. 3]metacyclophanes. 査読有り

未入力

Chem. Lett. 167 - 168 1999年04月

Transannular Interactions and Reactions of Dithia[3. 3]metacyclophanediazonium Salt. 査読有り

未入力

J. Chem. Res.(S), J. Chem. Res.(M) 604 - 605 2601-2 1999年04月

Diene Transmissive Hetero Diels-Alder Reaction of 1, 5-Diphenyl-1, 4-pentadiene-3-one. 査読有り

未入力

Heterocycles 50 661 - 666 1999年04月

Synthesis of Small-Sized Stilbenophanes and Their Transannular Delocalization. 査読有り

未入力

J. Org. Chem. 64 7246 - 7248 1999年04月

Evaluation of Transannular Interaction of[2. 3]Metacyclophane-diazonium Tetrafluoroborate and its Dediazoniated Derivatives. 査読有り

未入力

J. Chem. Res.(S), J. Chem. Res.(M) 78 - 79 437-448 1999年04月

Preparation and spectroscopic properties of five 7, 16-bis(azophenyl)tetraaza-[14]annulene nickel(II)complexes. 査読有り

未入力

Inorganica Chimica Acta 281 190 - 194 1998年04月

Immobilization of a Water-Soluble Host Molecule by Polyion Complexation with a Polymer. 査読有り

未入力

Aust. J. Chem. 51 1175 - 1178 1998年04月

Preparation and Conformational Properties of 1, 8-Bridged Fluorenophanes. 査読有り

未入力

Chem, Lett 603 - 604 1998年04月

Synthesis and Structure of Novel 1, 8-Bridged Fluorenophanes. 査読有り

未入力

J. Chem. Res. 168 - 169 1997年04月

Evaluation of Transannular Interaction of 5-Substituted[2. 2]metacyclophanes Carrying Diazonio Group on their Outer Position. 査読有り

未入力

J. Chem. Soc., Perkin Trans. 2 2141 - 2144 1997年04月

Estimation of Through-space Interaction between Two Aromatic Rings in Metacyclophanes. 査読有り

未入力

The Reports of Institute of Advanced Material Study, Kyushu University 11 153 - 158 1997年04月

Evaluation of Transannular Interaction in[2. 3]Metacyclophanes. 査読有り

未入力

Chem. Lett. 413 - 414 1997年04月

Synthesis of Water-soluble Diaza-1, 2, 5-Thiadiazolocyclophanes. 査読有り

未入力

Heterocyles 46 651 - 658 1997年04月

A Facile Synthesis of Dinitro[2. 2]metacyclophanes and its Partial Reduction. 査読有り

未入力

Liebigs Ann. 769 - 771 1996年04月

Synthesis, Conformation, and Reactivity of Ethylene-Bridged[1. 2. 2]Metacyclophanes. 査読有り

未入力

Chem. Lett. 425 - 426 1996年04月

Thiacalixarenes. 査読有り

未入力

J. Chem. Res. 22 - 23 1995年04月

[n. 2]Metacyclophanediquinones : Synthesis, Conformational Studies and Reduction to Tetrahydroxy[n. 2]metacyclophanes. 査読有り

未入力

Liebigs Ann. 995 - 1001 1995年04月

Unusual Balz-Schiemenn Reaction of[2. 2]Metacyckophanediazonium salts. 査読有り

未入力

J. Chem. Res. 460 - 461 1995年04月

Preparation and Spectral Properties of Disubstituted[2. 2]Metacyclophanes. 査読有り

未入力

J. Org. Chem. 60 4930 - 4931 1995年04月

Fluorescence Spectra and Coloration of a Europium(III)Hexaaza Macrocyclic Complex in Various Solvents. 査読有り

未入力

Polyhedron 13 159 - 161 1994年04月

The Stability Constants for the 18-Crown-6 complexes with[2. 2]Metacyclophanediazonium Salts. 査読有り

未入力

Bull. Chem. Soc. Jpn. 67 277 - 279 1994年04月

Facile Synthesis of 1, 8-and 1, 7-Bis(chloromethyl)fluorenes. 査読有り

未入力

Synthesis 205 - 206 1993年04月

Evaluation of Through-Space Interaction in[2. 2]Metacyclophanes by Diazo Coupling Reaction. 査読有り

未入力

J. Chem. Soc. Perkin Trans. 1 2211 - 2215 1993年04月

Nitration and Bromination of 8, 16-Dimethoxy[2. 2]metacyclophane. 査読有り

未入力

Chem. Express 7 469 - 472 1992年04月

Diazo Coupling of[2. 2]Metacyclophanes. 査読有り

未入力

Chem. Lett. 579 - 582 1992年04月

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